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Fe(3)O(4)/Graphene Composite Anode Material for Fast-Charging Li-Ion Batteries

Composite anode material based on Fe(3)O(4) and reduced graphene oxide is prepared by base-catalysed co-precipitation and sonochemical dispersion. Structural and morphological characterizations demonstrate an effective and homogeneous embedding of Fe(3)O(4) nanoparticles in the carbonaceous matrix....

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Autores principales: Staffolani, Antunes, Darjazi, Hamideh, Carbonari, Gilberto, Maroni, Fabio, Gabrielli, Serena, Nobili, Francesco
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8303447/
https://www.ncbi.nlm.nih.gov/pubmed/34299590
http://dx.doi.org/10.3390/molecules26144316
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author Staffolani, Antunes
Darjazi, Hamideh
Carbonari, Gilberto
Maroni, Fabio
Gabrielli, Serena
Nobili, Francesco
author_facet Staffolani, Antunes
Darjazi, Hamideh
Carbonari, Gilberto
Maroni, Fabio
Gabrielli, Serena
Nobili, Francesco
author_sort Staffolani, Antunes
collection PubMed
description Composite anode material based on Fe(3)O(4) and reduced graphene oxide is prepared by base-catalysed co-precipitation and sonochemical dispersion. Structural and morphological characterizations demonstrate an effective and homogeneous embedding of Fe(3)O(4) nanoparticles in the carbonaceous matrix. Electrochemical characterization highlights specific capacities higher than 1000 mAh g(−1) at 1C, while a capacity of 980 mAhg(−1) is retained at 4C, with outstanding cycling stability. These results demonstrate a synergistic effect by nanosize morphology of Fe(3)O(4) and inter-particle conductivity of graphene nanosheets, which also contribute to enhancing the mechanical and cycling stability of the electrode. The outstanding capacity delivered at high rates suggests a possible application of the anode material for high-power systems.
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spelling pubmed-83034472021-07-25 Fe(3)O(4)/Graphene Composite Anode Material for Fast-Charging Li-Ion Batteries Staffolani, Antunes Darjazi, Hamideh Carbonari, Gilberto Maroni, Fabio Gabrielli, Serena Nobili, Francesco Molecules Article Composite anode material based on Fe(3)O(4) and reduced graphene oxide is prepared by base-catalysed co-precipitation and sonochemical dispersion. Structural and morphological characterizations demonstrate an effective and homogeneous embedding of Fe(3)O(4) nanoparticles in the carbonaceous matrix. Electrochemical characterization highlights specific capacities higher than 1000 mAh g(−1) at 1C, while a capacity of 980 mAhg(−1) is retained at 4C, with outstanding cycling stability. These results demonstrate a synergistic effect by nanosize morphology of Fe(3)O(4) and inter-particle conductivity of graphene nanosheets, which also contribute to enhancing the mechanical and cycling stability of the electrode. The outstanding capacity delivered at high rates suggests a possible application of the anode material for high-power systems. MDPI 2021-07-16 /pmc/articles/PMC8303447/ /pubmed/34299590 http://dx.doi.org/10.3390/molecules26144316 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Staffolani, Antunes
Darjazi, Hamideh
Carbonari, Gilberto
Maroni, Fabio
Gabrielli, Serena
Nobili, Francesco
Fe(3)O(4)/Graphene Composite Anode Material for Fast-Charging Li-Ion Batteries
title Fe(3)O(4)/Graphene Composite Anode Material for Fast-Charging Li-Ion Batteries
title_full Fe(3)O(4)/Graphene Composite Anode Material for Fast-Charging Li-Ion Batteries
title_fullStr Fe(3)O(4)/Graphene Composite Anode Material for Fast-Charging Li-Ion Batteries
title_full_unstemmed Fe(3)O(4)/Graphene Composite Anode Material for Fast-Charging Li-Ion Batteries
title_short Fe(3)O(4)/Graphene Composite Anode Material for Fast-Charging Li-Ion Batteries
title_sort fe(3)o(4)/graphene composite anode material for fast-charging li-ion batteries
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8303447/
https://www.ncbi.nlm.nih.gov/pubmed/34299590
http://dx.doi.org/10.3390/molecules26144316
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