Enhanced Performance of Carbon Molecular Sieve Membranes Incorporating Zeolite Nanocrystals for Air Separation

Three different zeolite nanocrystals (SAPO-34, PS-MFI and ETS-10) were incorporated into the polymer matrix (Matrimid(®) 5218) as polymer precursors, with the aim of fabricating mixed-matrix carbon molecular sieve membranes (CMSMs). These membranes are investigated for their potential for air separation process. Based on our gas permeation results, incorporating porous materials is feasible to improve O(2) permeability, owing to the creation of additional porosities in the resulting mixed-matrix CMSMs. Owing to this, the performance of the CMSM with 30 wt% PS-MFI loading is able to surpass the upper bound limit. This study demonstrates the feasibility of zeolite nanocrystals in improving O(2)/N(2) separation performance in CMSMs.