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Synthesis and Study on Ni-Co Phosphite/Activated Carbon Fabric Composited Materials with Controllable Nano-Structure for Hybrid Super-Capacitor Applications

The advantage of low resistivity and inactive binders makes binder-free electrode an excellent candidate for high-performance energy devices. A simple hydrothermal method was used to fabricate M(11)(HPO(3))(8)(OH)(6) (M: Ni and Co) (MHP) arrays combined with activated carbon fabric (ACF) without bin...

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Detalles Bibliográficos
Autores principales: Jin, Dalai, Zhou, Jiamin, Yang, Tianpeng, Li, Saisai, Wang, Lina, Cai, Yurong, Wang, Longcheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8304602/
https://www.ncbi.nlm.nih.gov/pubmed/34201582
http://dx.doi.org/10.3390/nano11071649
Descripción
Sumario:The advantage of low resistivity and inactive binders makes binder-free electrode an excellent candidate for high-performance energy devices. A simple hydrothermal method was used to fabricate M(11)(HPO(3))(8)(OH)(6) (M: Ni and Co) (MHP) arrays combined with activated carbon fabric (ACF) without binder. The structures of MHP can be easily tuned from bouquets to nano-sheets by the concentration of NaH(2)PO(2). The MHP/ACF composite materials with different structures showed the typical battery-type characteristic of anodic electrodes. In a three-electrode cell configuration, the MHP nano-sheet arrays/ACF composite has a higher capacity, of 1254 F/g, at a scan rate of 10 mA/cm(2) and shows better cycling stability: 84.3% remaining specific capacity after 1000 cycles of charge-discharge measurement. The composite is highly flexible, with almost the same electrochemical performance under stretching mode. The MHP/ACF composite@ACF hybrid supercapacitor can deliver the highest energy density, of 34.1 Wh·kg(−)(1), and a power density of 722 W·kg(−)(1) at 1 A·g(−)(1). As indicated by the results, MHP/ACF composite materials are excellent binder-free electrodes, candidates for flexible high-performance hybrid super-capacitor devices.