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Efficient Bulky Organo-Zinc Scorpionates for the Stereoselective Production of Poly(rac-lactide)s

The direct reaction of the highly sterically demanding acetamidinate-based NNN′-scorpionate protioligand Hphbp(t)amd [Hphbp(t)amd = N,N′-di-p-tolylbis(3,5-di-tertbutylpyrazole-1-yl)acetamidine] with one equiv. of ZnMe(2) proceeds in high yield to the mononuclear alkyl zinc complex [ZnMe(κ(3)-phbp(t)...

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Detalles Bibliográficos
Autores principales:	Navarro, Marta, Garcés, Andrés, Sánchez-Barba, Luis F., de la Cruz-Martínez, Felipe, Fernández-Baeza, Juan, Lara-Sánchez, Agustín
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8309543/ https://www.ncbi.nlm.nih.gov/pubmed/34301114 http://dx.doi.org/10.3390/polym13142356

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