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Highlighting Thermo-Elastic Effects in Confined Fluids

The recent identification of a finite shear elasticity in mesoscopic fluids has motivated the search of other solid-like properties of liquids. We present an innovative thermal approach of liquids. We identify a dynamic thermo-elastic mesoscopic behavior by building the thermal image produced by dif...

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Detalles Bibliográficos
Autores principales: Kume, Eni, Baroni, Patrick, Noirez, Laurence
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8309621/
https://www.ncbi.nlm.nih.gov/pubmed/34301137
http://dx.doi.org/10.3390/polym13142378
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author Kume, Eni
Baroni, Patrick
Noirez, Laurence
author_facet Kume, Eni
Baroni, Patrick
Noirez, Laurence
author_sort Kume, Eni
collection PubMed
description The recent identification of a finite shear elasticity in mesoscopic fluids has motivated the search of other solid-like properties of liquids. We present an innovative thermal approach of liquids. We identify a dynamic thermo-elastic mesoscopic behavior by building the thermal image produced by different liquids upon applying a low frequency mechanical shear field. We selected three fluids: a low molecular weight polybutylacrylate (PBuA), polypropyleneglycol (PPG), and glycerol. We demonstrate that a part of the energy of the shear strain is converted in cold and hot shear bands varying synchronously with the applied shear field. This thermodynamic change suggests a coupling to shear elastic modes in agreement with the low frequency shear elasticity theoretically foreseen and experimentally demonstrated.
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spelling pubmed-83096212021-07-25 Highlighting Thermo-Elastic Effects in Confined Fluids Kume, Eni Baroni, Patrick Noirez, Laurence Polymers (Basel) Article The recent identification of a finite shear elasticity in mesoscopic fluids has motivated the search of other solid-like properties of liquids. We present an innovative thermal approach of liquids. We identify a dynamic thermo-elastic mesoscopic behavior by building the thermal image produced by different liquids upon applying a low frequency mechanical shear field. We selected three fluids: a low molecular weight polybutylacrylate (PBuA), polypropyleneglycol (PPG), and glycerol. We demonstrate that a part of the energy of the shear strain is converted in cold and hot shear bands varying synchronously with the applied shear field. This thermodynamic change suggests a coupling to shear elastic modes in agreement with the low frequency shear elasticity theoretically foreseen and experimentally demonstrated. MDPI 2021-07-20 /pmc/articles/PMC8309621/ /pubmed/34301137 http://dx.doi.org/10.3390/polym13142378 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Kume, Eni
Baroni, Patrick
Noirez, Laurence
Highlighting Thermo-Elastic Effects in Confined Fluids
title Highlighting Thermo-Elastic Effects in Confined Fluids
title_full Highlighting Thermo-Elastic Effects in Confined Fluids
title_fullStr Highlighting Thermo-Elastic Effects in Confined Fluids
title_full_unstemmed Highlighting Thermo-Elastic Effects in Confined Fluids
title_short Highlighting Thermo-Elastic Effects in Confined Fluids
title_sort highlighting thermo-elastic effects in confined fluids
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8309621/
https://www.ncbi.nlm.nih.gov/pubmed/34301137
http://dx.doi.org/10.3390/polym13142378
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