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Highlighting Thermo-Elastic Effects in Confined Fluids
The recent identification of a finite shear elasticity in mesoscopic fluids has motivated the search of other solid-like properties of liquids. We present an innovative thermal approach of liquids. We identify a dynamic thermo-elastic mesoscopic behavior by building the thermal image produced by dif...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8309621/ https://www.ncbi.nlm.nih.gov/pubmed/34301137 http://dx.doi.org/10.3390/polym13142378 |
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author | Kume, Eni Baroni, Patrick Noirez, Laurence |
author_facet | Kume, Eni Baroni, Patrick Noirez, Laurence |
author_sort | Kume, Eni |
collection | PubMed |
description | The recent identification of a finite shear elasticity in mesoscopic fluids has motivated the search of other solid-like properties of liquids. We present an innovative thermal approach of liquids. We identify a dynamic thermo-elastic mesoscopic behavior by building the thermal image produced by different liquids upon applying a low frequency mechanical shear field. We selected three fluids: a low molecular weight polybutylacrylate (PBuA), polypropyleneglycol (PPG), and glycerol. We demonstrate that a part of the energy of the shear strain is converted in cold and hot shear bands varying synchronously with the applied shear field. This thermodynamic change suggests a coupling to shear elastic modes in agreement with the low frequency shear elasticity theoretically foreseen and experimentally demonstrated. |
format | Online Article Text |
id | pubmed-8309621 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-83096212021-07-25 Highlighting Thermo-Elastic Effects in Confined Fluids Kume, Eni Baroni, Patrick Noirez, Laurence Polymers (Basel) Article The recent identification of a finite shear elasticity in mesoscopic fluids has motivated the search of other solid-like properties of liquids. We present an innovative thermal approach of liquids. We identify a dynamic thermo-elastic mesoscopic behavior by building the thermal image produced by different liquids upon applying a low frequency mechanical shear field. We selected three fluids: a low molecular weight polybutylacrylate (PBuA), polypropyleneglycol (PPG), and glycerol. We demonstrate that a part of the energy of the shear strain is converted in cold and hot shear bands varying synchronously with the applied shear field. This thermodynamic change suggests a coupling to shear elastic modes in agreement with the low frequency shear elasticity theoretically foreseen and experimentally demonstrated. MDPI 2021-07-20 /pmc/articles/PMC8309621/ /pubmed/34301137 http://dx.doi.org/10.3390/polym13142378 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Kume, Eni Baroni, Patrick Noirez, Laurence Highlighting Thermo-Elastic Effects in Confined Fluids |
title | Highlighting Thermo-Elastic Effects in Confined Fluids |
title_full | Highlighting Thermo-Elastic Effects in Confined Fluids |
title_fullStr | Highlighting Thermo-Elastic Effects in Confined Fluids |
title_full_unstemmed | Highlighting Thermo-Elastic Effects in Confined Fluids |
title_short | Highlighting Thermo-Elastic Effects in Confined Fluids |
title_sort | highlighting thermo-elastic effects in confined fluids |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8309621/ https://www.ncbi.nlm.nih.gov/pubmed/34301137 http://dx.doi.org/10.3390/polym13142378 |
work_keys_str_mv | AT kumeeni highlightingthermoelasticeffectsinconfinedfluids AT baronipatrick highlightingthermoelasticeffectsinconfinedfluids AT noirezlaurence highlightingthermoelasticeffectsinconfinedfluids |