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Following Metal-to-Ligand Charge-Transfer Dynamics with Ligand and Spin Specificity Using Femtosecond Resonant Inelastic X-ray Scattering at the Nitrogen K-Edge
[Image: see text] We demonstrate for the case of photoexcited [Ru(2,2′-bipyridine)(3)](2+) how femtosecond resonant inelastic X-ray scattering (RIXS) at the ligand K-edge allows one to uniquely probe changes in the valence electronic structure following a metal-to-ligand charge-transfer (MLCT) excit...
Autores principales: | Jay, Raphael M., Eckert, Sebastian, Van Kuiken, Benjamin E., Ochmann, Miguel, Hantschmann, Markus, Cordones, Amy A., Cho, Hana, Hong, Kiryong, Ma, Rory, Lee, Jae Hyuk, Dakovski, Georgi L., Turner, Joshua J., Minitti, Michael P., Quevedo, Wilson, Pietzsch, Annette, Beye, Martin, Kim, Tae Kyu, Schoenlein, Robert W., Wernet, Philippe, Föhlisch, Alexander, Huse, Nils |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8312498/ https://www.ncbi.nlm.nih.gov/pubmed/34260255 http://dx.doi.org/10.1021/acs.jpclett.1c01401 |
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