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Metal–Dithiolene Bonding Contributions to Pyranopterin Molybdenum Enzyme Reactivity
Here we highlight past work on metal-dithiolene interactions and how the unique electronic structure of the metal-dithiolene unit contributes to both the oxidative and reductive half reactions in pyranopterin molybdenum and tungsten enzymes. The metallodithiolene electronic structures detailed here...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8318340/ https://www.ncbi.nlm.nih.gov/pubmed/34327225 http://dx.doi.org/10.3390/inorganics8030019 |