A Multifunctional 3D Supermolecular Co Coordination Polymer With Potential for CO(2) Adsorption, Antibacterial Activity, and Selective Sensing of Fe(3+)/Cr(3+) Ions and TNP

A 3D supermolecular structure [Co(3)(L)(2) (2,2′-bipy)(2)](DMF)(3)(H(2)O)(3) 1) (H(3)L = 4,4′,4″-nitrilotribenzoic acid) has been constructed based on H(3)L, and 2,2′-bipy ligands under solvothermal conditions. Compound 1 can be described as a (3, 6)-connected kgd topology with a Schläfli symbol (4(...

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Autores principales: Zhou, Xiaojing, Liu, Lili, Kou, Hang, Zheng, Shimei, Song, Mingjun, Lu, Jitao, Tai, Xishi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8321245/
https://www.ncbi.nlm.nih.gov/pubmed/34336785
http://dx.doi.org/10.3389/fchem.2021.678993
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author Zhou, Xiaojing
Liu, Lili
Kou, Hang
Zheng, Shimei
Song, Mingjun
Lu, Jitao
Tai, Xishi
author_facet Zhou, Xiaojing
Liu, Lili
Kou, Hang
Zheng, Shimei
Song, Mingjun
Lu, Jitao
Tai, Xishi
author_sort Zhou, Xiaojing
collection PubMed
description A 3D supermolecular structure [Co(3)(L)(2) (2,2′-bipy)(2)](DMF)(3)(H(2)O)(3) 1) (H(3)L = 4,4′,4″-nitrilotribenzoic acid) has been constructed based on H(3)L, and 2,2′-bipy ligands under solvothermal conditions. Compound 1 can be described as a (3, 6)-connected kgd topology with a Schläfli symbol (4(3))(2)(4(6).6(6).8(3)) formed by [Co(3)(CO(2))(6)] secondary building units. The adsorption properties of the activated sample 1a has been studied; the result shows that 1a has a high adsorption ability: the CO(2) uptakes were 74 cm(3)·g(−1) at 273 K, 50 cm(3)·g(−1) at 298 K, the isosteric heat of adsorption (Q(st)) is 25.5 kJ mol(−1) at zero loading, and the N(2) adsorption at 77 K, 1 bar is 307 cm(3) g(−1). Magnetic measurements showed the existence of an antiferromagnetic exchange interaction in compound 1, besides compound 1 exhibits effective luminescent performance for Fe(3+)/Cr(3+) and TNP.
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spelling pubmed-83212452021-07-30 A Multifunctional 3D Supermolecular Co Coordination Polymer With Potential for CO(2) Adsorption, Antibacterial Activity, and Selective Sensing of Fe(3+)/Cr(3+) Ions and TNP Zhou, Xiaojing Liu, Lili Kou, Hang Zheng, Shimei Song, Mingjun Lu, Jitao Tai, Xishi Front Chem Chemistry A 3D supermolecular structure [Co(3)(L)(2) (2,2′-bipy)(2)](DMF)(3)(H(2)O)(3) 1) (H(3)L = 4,4′,4″-nitrilotribenzoic acid) has been constructed based on H(3)L, and 2,2′-bipy ligands under solvothermal conditions. Compound 1 can be described as a (3, 6)-connected kgd topology with a Schläfli symbol (4(3))(2)(4(6).6(6).8(3)) formed by [Co(3)(CO(2))(6)] secondary building units. The adsorption properties of the activated sample 1a has been studied; the result shows that 1a has a high adsorption ability: the CO(2) uptakes were 74 cm(3)·g(−1) at 273 K, 50 cm(3)·g(−1) at 298 K, the isosteric heat of adsorption (Q(st)) is 25.5 kJ mol(−1) at zero loading, and the N(2) adsorption at 77 K, 1 bar is 307 cm(3) g(−1). Magnetic measurements showed the existence of an antiferromagnetic exchange interaction in compound 1, besides compound 1 exhibits effective luminescent performance for Fe(3+)/Cr(3+) and TNP. Frontiers Media S.A. 2021-07-15 /pmc/articles/PMC8321245/ /pubmed/34336785 http://dx.doi.org/10.3389/fchem.2021.678993 Text en Copyright © 2021 Zhou, Liu, Kou, Zheng, Song, Lu and Tai. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Zhou, Xiaojing
Liu, Lili
Kou, Hang
Zheng, Shimei
Song, Mingjun
Lu, Jitao
Tai, Xishi
A Multifunctional 3D Supermolecular Co Coordination Polymer With Potential for CO(2) Adsorption, Antibacterial Activity, and Selective Sensing of Fe(3+)/Cr(3+) Ions and TNP
title A Multifunctional 3D Supermolecular Co Coordination Polymer With Potential for CO(2) Adsorption, Antibacterial Activity, and Selective Sensing of Fe(3+)/Cr(3+) Ions and TNP
title_full A Multifunctional 3D Supermolecular Co Coordination Polymer With Potential for CO(2) Adsorption, Antibacterial Activity, and Selective Sensing of Fe(3+)/Cr(3+) Ions and TNP
title_fullStr A Multifunctional 3D Supermolecular Co Coordination Polymer With Potential for CO(2) Adsorption, Antibacterial Activity, and Selective Sensing of Fe(3+)/Cr(3+) Ions and TNP
title_full_unstemmed A Multifunctional 3D Supermolecular Co Coordination Polymer With Potential for CO(2) Adsorption, Antibacterial Activity, and Selective Sensing of Fe(3+)/Cr(3+) Ions and TNP
title_short A Multifunctional 3D Supermolecular Co Coordination Polymer With Potential for CO(2) Adsorption, Antibacterial Activity, and Selective Sensing of Fe(3+)/Cr(3+) Ions and TNP
title_sort multifunctional 3d supermolecular co coordination polymer with potential for co(2) adsorption, antibacterial activity, and selective sensing of fe(3+)/cr(3+) ions and tnp
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8321245/
https://www.ncbi.nlm.nih.gov/pubmed/34336785
http://dx.doi.org/10.3389/fchem.2021.678993
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