Second-Generation Light-Fueled Supramolecular Pump

[Image: see text] We describe the modular design of a pseudorotaxane-based supramolecular pump and its photochemically driven autonomous nonequilibrium operation in a dissipative regime. These properties derive from careful engineering of the energy maxima and minima along the threading coordinate a...

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Detalles Bibliográficos
Autores principales: Canton, Martina, Groppi, Jessica, Casimiro, Lorenzo, Corra, Stefano, Baroncini, Massimo, Silvi, Serena, Credi, Alberto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8323096/
https://www.ncbi.nlm.nih.gov/pubmed/34282901
http://dx.doi.org/10.1021/jacs.1c06027
Descripción
Sumario:[Image: see text] We describe the modular design of a pseudorotaxane-based supramolecular pump and its photochemically driven autonomous nonequilibrium operation in a dissipative regime. These properties derive from careful engineering of the energy maxima and minima along the threading coordinate and their light-triggered modulation. Unlike its precursor, this second-generation system is amenable to functionalization for integration into more complex devices.

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