Second-Generation Light-Fueled Supramolecular Pump

[Image: see text] We describe the modular design of a pseudorotaxane-based supramolecular pump and its photochemically driven autonomous nonequilibrium operation in a dissipative regime. These properties derive from careful engineering of the energy maxima and minima along the threading coordinate a...

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Autores principales: Canton, Martina, Groppi, Jessica, Casimiro, Lorenzo, Corra, Stefano, Baroncini, Massimo, Silvi, Serena, Credi, Alberto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8323096/
https://www.ncbi.nlm.nih.gov/pubmed/34282901
http://dx.doi.org/10.1021/jacs.1c06027
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author Canton, Martina
Groppi, Jessica
Casimiro, Lorenzo
Corra, Stefano
Baroncini, Massimo
Silvi, Serena
Credi, Alberto
author_facet Canton, Martina
Groppi, Jessica
Casimiro, Lorenzo
Corra, Stefano
Baroncini, Massimo
Silvi, Serena
Credi, Alberto
author_sort Canton, Martina
collection PubMed
description [Image: see text] We describe the modular design of a pseudorotaxane-based supramolecular pump and its photochemically driven autonomous nonequilibrium operation in a dissipative regime. These properties derive from careful engineering of the energy maxima and minima along the threading coordinate and their light-triggered modulation. Unlike its precursor, this second-generation system is amenable to functionalization for integration into more complex devices.
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spelling pubmed-83230962021-08-02 Second-Generation Light-Fueled Supramolecular Pump Canton, Martina Groppi, Jessica Casimiro, Lorenzo Corra, Stefano Baroncini, Massimo Silvi, Serena Credi, Alberto J Am Chem Soc [Image: see text] We describe the modular design of a pseudorotaxane-based supramolecular pump and its photochemically driven autonomous nonequilibrium operation in a dissipative regime. These properties derive from careful engineering of the energy maxima and minima along the threading coordinate and their light-triggered modulation. Unlike its precursor, this second-generation system is amenable to functionalization for integration into more complex devices. American Chemical Society 2021-07-20 2021-07-28 /pmc/articles/PMC8323096/ /pubmed/34282901 http://dx.doi.org/10.1021/jacs.1c06027 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Canton, Martina
Groppi, Jessica
Casimiro, Lorenzo
Corra, Stefano
Baroncini, Massimo
Silvi, Serena
Credi, Alberto
Second-Generation Light-Fueled Supramolecular Pump
title Second-Generation Light-Fueled Supramolecular Pump
title_full Second-Generation Light-Fueled Supramolecular Pump
title_fullStr Second-Generation Light-Fueled Supramolecular Pump
title_full_unstemmed Second-Generation Light-Fueled Supramolecular Pump
title_short Second-Generation Light-Fueled Supramolecular Pump
title_sort second-generation light-fueled supramolecular pump
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8323096/
https://www.ncbi.nlm.nih.gov/pubmed/34282901
http://dx.doi.org/10.1021/jacs.1c06027
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