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Utilization of cellulose in tobacco (Nicotiana tobacum) stalks for nitrocellulose production

This research explains the conversion of waste tobacco stalks into nitrocellulose to try to recover as much chemical potential contained in the biomass material as possible. Simple pioneering experiments were conducted using pulping tobacco stalks with a moisture content of 10.17 wt% and the soda pu...

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Detalles Bibliográficos
Autores principales: Muvhiiwa, Ralph, Mawere, Emmanuel, Moyo, Langa Bright, Tshuma, Lawrencia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8327662/
https://www.ncbi.nlm.nih.gov/pubmed/34377854
http://dx.doi.org/10.1016/j.heliyon.2021.e07598
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author Muvhiiwa, Ralph
Mawere, Emmanuel
Moyo, Langa Bright
Tshuma, Lawrencia
author_facet Muvhiiwa, Ralph
Mawere, Emmanuel
Moyo, Langa Bright
Tshuma, Lawrencia
author_sort Muvhiiwa, Ralph
collection PubMed
description This research explains the conversion of waste tobacco stalks into nitrocellulose to try to recover as much chemical potential contained in the biomass material as possible. Simple pioneering experiments were conducted using pulping tobacco stalks with a moisture content of 10.17 wt% and the soda pulping method being applied to produce cellulose pulp. The cellulose pulp was bleached using calcium hypochlorite to produce a dry white lignin-free pulp, which was subjected to nitration. The mixture used was 67% nitric acid and 98% sulphuric acid, and the acid ratio was varied between 3:7 and 7:3 v/v. Nitration time was varied between 5 and 25 min. This process produced nitrocellulose with all the various conditions. The nitrocellulose obtained with nitrogen content between 11 – 11.5% v/v was characterized using its solubility in acetone. An optimum nitrating mixture of 1:1 v/v with a nitration time of 5 min was used to produce nitrocellulose from tobacco stalks using soda pulping. The results show a great potential for tobacco farming countries to reduce their nitrocellulose import bill using this process.
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spelling pubmed-83276622021-08-09 Utilization of cellulose in tobacco (Nicotiana tobacum) stalks for nitrocellulose production Muvhiiwa, Ralph Mawere, Emmanuel Moyo, Langa Bright Tshuma, Lawrencia Heliyon Research Article This research explains the conversion of waste tobacco stalks into nitrocellulose to try to recover as much chemical potential contained in the biomass material as possible. Simple pioneering experiments were conducted using pulping tobacco stalks with a moisture content of 10.17 wt% and the soda pulping method being applied to produce cellulose pulp. The cellulose pulp was bleached using calcium hypochlorite to produce a dry white lignin-free pulp, which was subjected to nitration. The mixture used was 67% nitric acid and 98% sulphuric acid, and the acid ratio was varied between 3:7 and 7:3 v/v. Nitration time was varied between 5 and 25 min. This process produced nitrocellulose with all the various conditions. The nitrocellulose obtained with nitrogen content between 11 – 11.5% v/v was characterized using its solubility in acetone. An optimum nitrating mixture of 1:1 v/v with a nitration time of 5 min was used to produce nitrocellulose from tobacco stalks using soda pulping. The results show a great potential for tobacco farming countries to reduce their nitrocellulose import bill using this process. Elsevier 2021-07-16 /pmc/articles/PMC8327662/ /pubmed/34377854 http://dx.doi.org/10.1016/j.heliyon.2021.e07598 Text en © 2021 The Author(s) https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Research Article
Muvhiiwa, Ralph
Mawere, Emmanuel
Moyo, Langa Bright
Tshuma, Lawrencia
Utilization of cellulose in tobacco (Nicotiana tobacum) stalks for nitrocellulose production
title Utilization of cellulose in tobacco (Nicotiana tobacum) stalks for nitrocellulose production
title_full Utilization of cellulose in tobacco (Nicotiana tobacum) stalks for nitrocellulose production
title_fullStr Utilization of cellulose in tobacco (Nicotiana tobacum) stalks for nitrocellulose production
title_full_unstemmed Utilization of cellulose in tobacco (Nicotiana tobacum) stalks for nitrocellulose production
title_short Utilization of cellulose in tobacco (Nicotiana tobacum) stalks for nitrocellulose production
title_sort utilization of cellulose in tobacco (nicotiana tobacum) stalks for nitrocellulose production
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8327662/
https://www.ncbi.nlm.nih.gov/pubmed/34377854
http://dx.doi.org/10.1016/j.heliyon.2021.e07598
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