Dynamic parallel kinetic resolution of α-ferrocenyl cation initiated by chiral Brønsted acid catalyst

The dynamic parallel kinetic resolution (DPKR) of an α-ferrocenyl cation intermediate under the influence of a chiral conjugate base of a chiral phosphoric acid catalyst has been demonstrated in an S(N)1 type substitution reaction of a racemic ferrocenyl derivative with a nitrogen nucleophile. The p...

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Detalles Bibliográficos
Autores principales: Toda, Yasunori, Korenaga, Toshinobu, Obayashi, Ren, Kikuchi, Jun, Terada, Masahiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8336484/
https://www.ncbi.nlm.nih.gov/pubmed/34447532
http://dx.doi.org/10.1039/d1sc02122b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8336484/
https://www.ncbi.nlm.nih.gov/pubmed/34447532
http://dx.doi.org/10.1039/d1sc02122b

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