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Dynamic parallel kinetic resolution of α-ferrocenyl cation initiated by chiral Brønsted acid catalyst

The dynamic parallel kinetic resolution (DPKR) of an α-ferrocenyl cation intermediate under the influence of a chiral conjugate base of a chiral phosphoric acid catalyst has been demonstrated in an S(N)1 type substitution reaction of a racemic ferrocenyl derivative with a nitrogen nucleophile. The p...

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Detalles Bibliográficos
Autores principales:	Toda, Yasunori, Korenaga, Toshinobu, Obayashi, Ren, Kikuchi, Jun, Terada, Masahiro
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8336484/ https://www.ncbi.nlm.nih.gov/pubmed/34447532 http://dx.doi.org/10.1039/d1sc02122b

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