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Highly Resolved and Robust Dynamic X‐Ray Imaging Using Perovskite Glass‐Ceramic Scintillator with Reduced Light Scattering

All‐inorganic perovskite quantum dots (QDs) CsPbX(3) (X = Cl, Br, and I) have recently emerged as a new promising class of X‐ray scintillators. However, the instability of perovskite QDs and the strong optical scattering of the thick opaque QD scintillator film imped it to realize high‐quality and r...

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Autores principales: Ma, Wenbo, Jiang, Tingming, Yang, Ze, Zhang, Hao, Su, Yirong, Chen, Zeng, Chen, Xinya, Ma, Yaoguang, Zhu, Wenjuan, Yu, Xue, Zhu, Haiming, Qiu, Jianbei, Liu, Xu, Xu, Xuhui, Yang, Yang (Michael)
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8336613/
https://www.ncbi.nlm.nih.gov/pubmed/34075729
http://dx.doi.org/10.1002/advs.202003728
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author Ma, Wenbo
Jiang, Tingming
Yang, Ze
Zhang, Hao
Su, Yirong
Chen, Zeng
Chen, Xinya
Ma, Yaoguang
Zhu, Wenjuan
Yu, Xue
Zhu, Haiming
Qiu, Jianbei
Liu, Xu
Xu, Xuhui
Yang, Yang (Michael)
author_facet Ma, Wenbo
Jiang, Tingming
Yang, Ze
Zhang, Hao
Su, Yirong
Chen, Zeng
Chen, Xinya
Ma, Yaoguang
Zhu, Wenjuan
Yu, Xue
Zhu, Haiming
Qiu, Jianbei
Liu, Xu
Xu, Xuhui
Yang, Yang (Michael)
author_sort Ma, Wenbo
collection PubMed
description All‐inorganic perovskite quantum dots (QDs) CsPbX(3) (X = Cl, Br, and I) have recently emerged as a new promising class of X‐ray scintillators. However, the instability of perovskite QDs and the strong optical scattering of the thick opaque QD scintillator film imped it to realize high‐quality and robust X‐ray image. Herein, the europium (Eu) doped CsPbBr(3) QDs are in situ grown inside transparent amorphous matrix to form glass‐ceramic (GC) scintillator with glass phase serving as both matrix and encapsulation for the perovskite QD scintillators. The small amount of Eu dopant optimizes the crystallization of CsPbBr(3) QDs and makes their distribution more uniform in the glass matrix, which can significantly reduce the light scattering and also enhance the photoluminescence emission of CsPbBr(3) QDs. As a result, a remarkably high spatial resolution of 15.0 lp mm(−1) is realized thanks to the reduced light scattering, which is so far a record resolution for perovskite scintillator based X‐ray imaging, and the scintillation stability is also significantly improved compared to the bare perovskite QD scintillators. Those results provide an effective platform particularly for the emerging perovskite nanocrystal scintillators to reduce light scattering and improve radiation hardness.
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spelling pubmed-83366132021-08-11 Highly Resolved and Robust Dynamic X‐Ray Imaging Using Perovskite Glass‐Ceramic Scintillator with Reduced Light Scattering Ma, Wenbo Jiang, Tingming Yang, Ze Zhang, Hao Su, Yirong Chen, Zeng Chen, Xinya Ma, Yaoguang Zhu, Wenjuan Yu, Xue Zhu, Haiming Qiu, Jianbei Liu, Xu Xu, Xuhui Yang, Yang (Michael) Adv Sci (Weinh) Communications All‐inorganic perovskite quantum dots (QDs) CsPbX(3) (X = Cl, Br, and I) have recently emerged as a new promising class of X‐ray scintillators. However, the instability of perovskite QDs and the strong optical scattering of the thick opaque QD scintillator film imped it to realize high‐quality and robust X‐ray image. Herein, the europium (Eu) doped CsPbBr(3) QDs are in situ grown inside transparent amorphous matrix to form glass‐ceramic (GC) scintillator with glass phase serving as both matrix and encapsulation for the perovskite QD scintillators. The small amount of Eu dopant optimizes the crystallization of CsPbBr(3) QDs and makes their distribution more uniform in the glass matrix, which can significantly reduce the light scattering and also enhance the photoluminescence emission of CsPbBr(3) QDs. As a result, a remarkably high spatial resolution of 15.0 lp mm(−1) is realized thanks to the reduced light scattering, which is so far a record resolution for perovskite scintillator based X‐ray imaging, and the scintillation stability is also significantly improved compared to the bare perovskite QD scintillators. Those results provide an effective platform particularly for the emerging perovskite nanocrystal scintillators to reduce light scattering and improve radiation hardness. John Wiley and Sons Inc. 2021-06-02 /pmc/articles/PMC8336613/ /pubmed/34075729 http://dx.doi.org/10.1002/advs.202003728 Text en © 2021 The Authors. Advanced Science published by Wiley‐VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Ma, Wenbo
Jiang, Tingming
Yang, Ze
Zhang, Hao
Su, Yirong
Chen, Zeng
Chen, Xinya
Ma, Yaoguang
Zhu, Wenjuan
Yu, Xue
Zhu, Haiming
Qiu, Jianbei
Liu, Xu
Xu, Xuhui
Yang, Yang (Michael)
Highly Resolved and Robust Dynamic X‐Ray Imaging Using Perovskite Glass‐Ceramic Scintillator with Reduced Light Scattering
title Highly Resolved and Robust Dynamic X‐Ray Imaging Using Perovskite Glass‐Ceramic Scintillator with Reduced Light Scattering
title_full Highly Resolved and Robust Dynamic X‐Ray Imaging Using Perovskite Glass‐Ceramic Scintillator with Reduced Light Scattering
title_fullStr Highly Resolved and Robust Dynamic X‐Ray Imaging Using Perovskite Glass‐Ceramic Scintillator with Reduced Light Scattering
title_full_unstemmed Highly Resolved and Robust Dynamic X‐Ray Imaging Using Perovskite Glass‐Ceramic Scintillator with Reduced Light Scattering
title_short Highly Resolved and Robust Dynamic X‐Ray Imaging Using Perovskite Glass‐Ceramic Scintillator with Reduced Light Scattering
title_sort highly resolved and robust dynamic x‐ray imaging using perovskite glass‐ceramic scintillator with reduced light scattering
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8336613/
https://www.ncbi.nlm.nih.gov/pubmed/34075729
http://dx.doi.org/10.1002/advs.202003728
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