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Comparative Study on the Hydrogenation of Naphthalene over Both Al(2)O(3)-Supported Pd and NiMo Catalysts against a Novel LDH-Derived Ni-MMO-Supported Mo Catalyst
[Image: see text] Naphthalene hydrogenation was studied over a novel Ni–Al-layered double hydroxide-derived Mo-doped mixed metal oxide (Mo-MMO), contrasted against bifunctional NiMo/Al(2)O(3), and Pd-doped Al(2)O(3) catalysts, the latter of which with Pd loadings of 1, 2, and 5 wt %. Reaction rate c...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8340395/ https://www.ncbi.nlm.nih.gov/pubmed/34368590 http://dx.doi.org/10.1021/acsomega.1c03083 |
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author | Claydon, Ryan M. Roman-Ramirez, Luis A. Wood, Joseph |
author_facet | Claydon, Ryan M. Roman-Ramirez, Luis A. Wood, Joseph |
author_sort | Claydon, Ryan M. |
collection | PubMed |
description | [Image: see text] Naphthalene hydrogenation was studied over a novel Ni–Al-layered double hydroxide-derived Mo-doped mixed metal oxide (Mo-MMO), contrasted against bifunctional NiMo/Al(2)O(3), and Pd-doped Al(2)O(3) catalysts, the latter of which with Pd loadings of 1, 2, and 5 wt %. Reaction rate constants were derived from a pseudo-first-order kinetic pathway describing a two-step hydrogenation pathway to tetralin (k(1)) and decalin (k(2)). The Mo-MMO catalyst achieved comparable reaction rates to Pd(2%)/Al(2)O(3) at double concentration. When using Pd(5%)/Al(2)O(3), tetralin hydrogenation was favored over naphthalene hydrogenation culminating in a k(2) value of 0.224 compared to a k(1) value of 0.069. Ni- and Mo-based catalysts produced the most significant cis-decalin production, with Mo-MMO culminating at a cis/trans ratio of 0.62 as well as providing enhanced activity in naphthalene hydrogenation compared to NiMo/Al(2)O(3). Consequently, Mo-MMO presents an opportunity to generate more alkyl naphthenes in subsequent hydrodecyclization reactions and therefore a higher cetane number in transport fuels. This is contrasted by a preferential production of trans-decalin observed when using all of the Al(2)O(3)-supported Pd catalysts, as a result of octalin intermediate orientations on the catalyst surface as a function of the electronic properties of Pd catalysts. |
format | Online Article Text |
id | pubmed-8340395 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-83403952021-08-06 Comparative Study on the Hydrogenation of Naphthalene over Both Al(2)O(3)-Supported Pd and NiMo Catalysts against a Novel LDH-Derived Ni-MMO-Supported Mo Catalyst Claydon, Ryan M. Roman-Ramirez, Luis A. Wood, Joseph ACS Omega [Image: see text] Naphthalene hydrogenation was studied over a novel Ni–Al-layered double hydroxide-derived Mo-doped mixed metal oxide (Mo-MMO), contrasted against bifunctional NiMo/Al(2)O(3), and Pd-doped Al(2)O(3) catalysts, the latter of which with Pd loadings of 1, 2, and 5 wt %. Reaction rate constants were derived from a pseudo-first-order kinetic pathway describing a two-step hydrogenation pathway to tetralin (k(1)) and decalin (k(2)). The Mo-MMO catalyst achieved comparable reaction rates to Pd(2%)/Al(2)O(3) at double concentration. When using Pd(5%)/Al(2)O(3), tetralin hydrogenation was favored over naphthalene hydrogenation culminating in a k(2) value of 0.224 compared to a k(1) value of 0.069. Ni- and Mo-based catalysts produced the most significant cis-decalin production, with Mo-MMO culminating at a cis/trans ratio of 0.62 as well as providing enhanced activity in naphthalene hydrogenation compared to NiMo/Al(2)O(3). Consequently, Mo-MMO presents an opportunity to generate more alkyl naphthenes in subsequent hydrodecyclization reactions and therefore a higher cetane number in transport fuels. This is contrasted by a preferential production of trans-decalin observed when using all of the Al(2)O(3)-supported Pd catalysts, as a result of octalin intermediate orientations on the catalyst surface as a function of the electronic properties of Pd catalysts. American Chemical Society 2021-07-19 /pmc/articles/PMC8340395/ /pubmed/34368590 http://dx.doi.org/10.1021/acsomega.1c03083 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Claydon, Ryan M. Roman-Ramirez, Luis A. Wood, Joseph Comparative Study on the Hydrogenation of Naphthalene over Both Al(2)O(3)-Supported Pd and NiMo Catalysts against a Novel LDH-Derived Ni-MMO-Supported Mo Catalyst |
title | Comparative Study on the Hydrogenation of Naphthalene
over Both Al(2)O(3)-Supported Pd and NiMo
Catalysts against a Novel LDH-Derived Ni-MMO-Supported Mo Catalyst |
title_full | Comparative Study on the Hydrogenation of Naphthalene
over Both Al(2)O(3)-Supported Pd and NiMo
Catalysts against a Novel LDH-Derived Ni-MMO-Supported Mo Catalyst |
title_fullStr | Comparative Study on the Hydrogenation of Naphthalene
over Both Al(2)O(3)-Supported Pd and NiMo
Catalysts against a Novel LDH-Derived Ni-MMO-Supported Mo Catalyst |
title_full_unstemmed | Comparative Study on the Hydrogenation of Naphthalene
over Both Al(2)O(3)-Supported Pd and NiMo
Catalysts against a Novel LDH-Derived Ni-MMO-Supported Mo Catalyst |
title_short | Comparative Study on the Hydrogenation of Naphthalene
over Both Al(2)O(3)-Supported Pd and NiMo
Catalysts against a Novel LDH-Derived Ni-MMO-Supported Mo Catalyst |
title_sort | comparative study on the hydrogenation of naphthalene
over both al(2)o(3)-supported pd and nimo
catalysts against a novel ldh-derived ni-mmo-supported mo catalyst |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8340395/ https://www.ncbi.nlm.nih.gov/pubmed/34368590 http://dx.doi.org/10.1021/acsomega.1c03083 |
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