Synthesis and crystallographic studies of 2-(di­phenyl­phosphino­thio­yl)-2-(3-oxobut-1-en-yl)ferrocene

As a follow-up to our research on the chemistry of disubstituted ferrocene derivatives, the synthesis and the structure of the title compound, 2-(di­phenyl­phosphino­thio­yl)-2-(3-oxobut-1-en-yl)ferrocene, [Fe(C(5)H(5))(C(21)H(18)OPS)], are described. The mol­ecule is built up from a ferrocene unit...

Descripción completa

Detalles Bibliográficos
Autores principales: Bandyopadhyay, Uchchhal, Sundararaju, Basker, Poli, Rinaldo, Manoury, Eric, Daran, Jean-Claude
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8340968/
https://www.ncbi.nlm.nih.gov/pubmed/34422314
http://dx.doi.org/10.1107/S205698902100760X
_version_ 1783733855003344896
author Bandyopadhyay, Uchchhal
Sundararaju, Basker
Poli, Rinaldo
Manoury, Eric
Daran, Jean-Claude
author_facet Bandyopadhyay, Uchchhal
Sundararaju, Basker
Poli, Rinaldo
Manoury, Eric
Daran, Jean-Claude
author_sort Bandyopadhyay, Uchchhal
collection PubMed
description As a follow-up to our research on the chemistry of disubstituted ferrocene derivatives, the synthesis and the structure of the title compound, 2-(di­phenyl­phosphino­thio­yl)-2-(3-oxobut-1-en-yl)ferrocene, [Fe(C(5)H(5))(C(21)H(18)OPS)], are described. The mol­ecule is built up from a ferrocene unit disubstituted by an S-protected di­phenyl­phosphine group and by a methyl­vinyl­ketone chain. The crystal structure features weak C—H⋯O and C—H⋯S inter­actions, which build a two-dimensional network. This structure is compared to that of the related disubstituted di­phenyl­phosphino ferrocene.
format Online
Article
Text
id pubmed-8340968
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-83409682021-08-19 Synthesis and crystallographic studies of 2-(di­phenyl­phosphino­thio­yl)-2-(3-oxobut-1-en-yl)ferrocene Bandyopadhyay, Uchchhal Sundararaju, Basker Poli, Rinaldo Manoury, Eric Daran, Jean-Claude Acta Crystallogr E Crystallogr Commun Research Communications As a follow-up to our research on the chemistry of disubstituted ferrocene derivatives, the synthesis and the structure of the title compound, 2-(di­phenyl­phosphino­thio­yl)-2-(3-oxobut-1-en-yl)ferrocene, [Fe(C(5)H(5))(C(21)H(18)OPS)], are described. The mol­ecule is built up from a ferrocene unit disubstituted by an S-protected di­phenyl­phosphine group and by a methyl­vinyl­ketone chain. The crystal structure features weak C—H⋯O and C—H⋯S inter­actions, which build a two-dimensional network. This structure is compared to that of the related disubstituted di­phenyl­phosphino ferrocene. International Union of Crystallography 2021-07-30 /pmc/articles/PMC8340968/ /pubmed/34422314 http://dx.doi.org/10.1107/S205698902100760X Text en © Bandyopadhyay et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Bandyopadhyay, Uchchhal
Sundararaju, Basker
Poli, Rinaldo
Manoury, Eric
Daran, Jean-Claude
Synthesis and crystallographic studies of 2-(di­phenyl­phosphino­thio­yl)-2-(3-oxobut-1-en-yl)ferrocene
title Synthesis and crystallographic studies of 2-(di­phenyl­phosphino­thio­yl)-2-(3-oxobut-1-en-yl)ferrocene
title_full Synthesis and crystallographic studies of 2-(di­phenyl­phosphino­thio­yl)-2-(3-oxobut-1-en-yl)ferrocene
title_fullStr Synthesis and crystallographic studies of 2-(di­phenyl­phosphino­thio­yl)-2-(3-oxobut-1-en-yl)ferrocene
title_full_unstemmed Synthesis and crystallographic studies of 2-(di­phenyl­phosphino­thio­yl)-2-(3-oxobut-1-en-yl)ferrocene
title_short Synthesis and crystallographic studies of 2-(di­phenyl­phosphino­thio­yl)-2-(3-oxobut-1-en-yl)ferrocene
title_sort synthesis and crystallographic studies of 2-(di­phenyl­phosphino­thio­yl)-2-(3-oxobut-1-en-yl)ferrocene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8340968/
https://www.ncbi.nlm.nih.gov/pubmed/34422314
http://dx.doi.org/10.1107/S205698902100760X
work_keys_str_mv AT bandyopadhyayuchchhal synthesisandcrystallographicstudiesof2diphenylphosphinothioyl23oxobut1enylferrocene
AT sundararajubasker synthesisandcrystallographicstudiesof2diphenylphosphinothioyl23oxobut1enylferrocene
AT polirinaldo synthesisandcrystallographicstudiesof2diphenylphosphinothioyl23oxobut1enylferrocene
AT manouryeric synthesisandcrystallographicstudiesof2diphenylphosphinothioyl23oxobut1enylferrocene
AT daranjeanclaude synthesisandcrystallographicstudiesof2diphenylphosphinothioyl23oxobut1enylferrocene

Ejemplares similares