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Crystal structures of three N-acyl­hydrazone isomers

The crystal structures of three isomers of (E)-4-chloro-N-{2-[2-(chloro­benzyl­idene)hydrazin­yl]-2-oxoeth­yl}­benzene­sulfonamide, namely, (E)-4-chloro-N-{2-[2-(2-chloro­benzyl­idene)hydrazin­yl]-2-oxoeth­yl}­benzene­sulfonamide (I), (E)-4-chloro-N-{2-[2-(3-chloro­benzyl­idene)hydrazin­yl]-2-oxoeth...

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Autores principales: Purandara, H., Foro, Sabine, Thimme Gowda, B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8340974/
https://www.ncbi.nlm.nih.gov/pubmed/34422300
http://dx.doi.org/10.1107/S2056989021006885
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author Purandara, H.
Foro, Sabine
Thimme Gowda, B.
author_facet Purandara, H.
Foro, Sabine
Thimme Gowda, B.
author_sort Purandara, H.
collection PubMed
description The crystal structures of three isomers of (E)-4-chloro-N-{2-[2-(chloro­benzyl­idene)hydrazin­yl]-2-oxoeth­yl}­benzene­sulfonamide, namely, (E)-4-chloro-N-{2-[2-(2-chloro­benzyl­idene)hydrazin­yl]-2-oxoeth­yl}­benzene­sulfonamide (I), (E)-4-chloro-N-{2-[2-(3-chloro­benzyl­idene)hydrazin­yl]-2-oxoeth­yl}­benzene­sul­fon­amide (II) and (E)-4-chloro-N-{2-[2-(4-chloro­benzyl­idene)hydrazin­yl]-2-oxo­eth­yl}­benzene­sulfonamide (III), with the general formula C(15)H(13)Cl(2)N(3)O(3)S are described, with the chloro group in ortho, meta and para positions in the benzyl­idene benzene ring. All the three isomeric compounds crystallize in the centrosymmetric triclinic P [Image: see text] space group with one mol­ecule each in the asymmetric unit and two mol­ecules in the unit cell. The dihedral angles between the two phenyl rings are 11.09 (14), 53.79 (18) and 72.37 (11)° in (I), (II) and (III), respectively. The central part of the mol­ecule (–C—N—N=C–) is almost linear with C—N—N—C torsion angles of 179.1 (2), −169.5 (3) and 178.5 (2)° for (I), (II) and (III), respectively. In all the three crystals, the mol­ecules form inversion dimers with R (2) (2)(8) ring motifs, which are further augmented by C—H⋯O inter­actions.
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spelling pubmed-83409742021-08-19 Crystal structures of three N-acyl­hydrazone isomers Purandara, H. Foro, Sabine Thimme Gowda, B. Acta Crystallogr E Crystallogr Commun Research Communications The crystal structures of three isomers of (E)-4-chloro-N-{2-[2-(chloro­benzyl­idene)hydrazin­yl]-2-oxoeth­yl}­benzene­sulfonamide, namely, (E)-4-chloro-N-{2-[2-(2-chloro­benzyl­idene)hydrazin­yl]-2-oxoeth­yl}­benzene­sulfonamide (I), (E)-4-chloro-N-{2-[2-(3-chloro­benzyl­idene)hydrazin­yl]-2-oxoeth­yl}­benzene­sul­fon­amide (II) and (E)-4-chloro-N-{2-[2-(4-chloro­benzyl­idene)hydrazin­yl]-2-oxo­eth­yl}­benzene­sulfonamide (III), with the general formula C(15)H(13)Cl(2)N(3)O(3)S are described, with the chloro group in ortho, meta and para positions in the benzyl­idene benzene ring. All the three isomeric compounds crystallize in the centrosymmetric triclinic P [Image: see text] space group with one mol­ecule each in the asymmetric unit and two mol­ecules in the unit cell. The dihedral angles between the two phenyl rings are 11.09 (14), 53.79 (18) and 72.37 (11)° in (I), (II) and (III), respectively. The central part of the mol­ecule (–C—N—N=C–) is almost linear with C—N—N—C torsion angles of 179.1 (2), −169.5 (3) and 178.5 (2)° for (I), (II) and (III), respectively. In all the three crystals, the mol­ecules form inversion dimers with R (2) (2)(8) ring motifs, which are further augmented by C—H⋯O inter­actions. International Union of Crystallography 2021-07-09 /pmc/articles/PMC8340974/ /pubmed/34422300 http://dx.doi.org/10.1107/S2056989021006885 Text en © Purandara et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Purandara, H.
Foro, Sabine
Thimme Gowda, B.
Crystal structures of three N-acyl­hydrazone isomers
title Crystal structures of three N-acyl­hydrazone isomers
title_full Crystal structures of three N-acyl­hydrazone isomers
title_fullStr Crystal structures of three N-acyl­hydrazone isomers
title_full_unstemmed Crystal structures of three N-acyl­hydrazone isomers
title_short Crystal structures of three N-acyl­hydrazone isomers
title_sort crystal structures of three n-acyl­hydrazone isomers
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8340974/
https://www.ncbi.nlm.nih.gov/pubmed/34422300
http://dx.doi.org/10.1107/S2056989021006885
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