Crystal structure and Hirshfeld surface analysis of 1,3-bis­{2,2-di­chloro-1-[(E)-phenyl­diazen­yl]ethen­yl}benzene

In the mol­ecule of the title compound, C(22)H(14)Cl(4)N(4), the central benzene ring makes dihedral angles of 77.03 (9) and 81.42 (9)° with the two approximately planar 2,2-di­chloro-1-[(E)-phenyl­diazen­yl]vinyl groups. In the crystal, mol­ecules are linked by C—H⋯π, C—Cl⋯π, Cl⋯Cl and Cl⋯H inter­a...

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Autores principales: Shikhaliyev, Namiq Q., Atioğlu, Zeliha, Akkurt, Mehmet, Ahmadova, Nigar E., Askerov, Rizvan K., Bhattarai, Ajaya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8340979/
https://www.ncbi.nlm.nih.gov/pubmed/34422307
http://dx.doi.org/10.1107/S2056989021007192
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author Shikhaliyev, Namiq Q.
Atioğlu, Zeliha
Akkurt, Mehmet
Ahmadova, Nigar E.
Askerov, Rizvan K.
Bhattarai, Ajaya
author_facet Shikhaliyev, Namiq Q.
Atioğlu, Zeliha
Akkurt, Mehmet
Ahmadova, Nigar E.
Askerov, Rizvan K.
Bhattarai, Ajaya
author_sort Shikhaliyev, Namiq Q.
collection PubMed
description In the mol­ecule of the title compound, C(22)H(14)Cl(4)N(4), the central benzene ring makes dihedral angles of 77.03 (9) and 81.42 (9)° with the two approximately planar 2,2-di­chloro-1-[(E)-phenyl­diazen­yl]vinyl groups. In the crystal, mol­ecules are linked by C—H⋯π, C—Cl⋯π, Cl⋯Cl and Cl⋯H inter­actions, forming a three-dimensional network. The Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H⋯H (30.4%), C⋯H/H⋯C (20.4%), Cl⋯H/H⋯Cl (19.4%), Cl⋯Cl (7.8%) and Cl⋯C/C⋯Cl (7.3%) inter­actions.
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spelling pubmed-83409792021-08-19 Crystal structure and Hirshfeld surface analysis of 1,3-bis­{2,2-di­chloro-1-[(E)-phenyl­diazen­yl]ethen­yl}benzene Shikhaliyev, Namiq Q. Atioğlu, Zeliha Akkurt, Mehmet Ahmadova, Nigar E. Askerov, Rizvan K. Bhattarai, Ajaya Acta Crystallogr E Crystallogr Commun Research Communications In the mol­ecule of the title compound, C(22)H(14)Cl(4)N(4), the central benzene ring makes dihedral angles of 77.03 (9) and 81.42 (9)° with the two approximately planar 2,2-di­chloro-1-[(E)-phenyl­diazen­yl]vinyl groups. In the crystal, mol­ecules are linked by C—H⋯π, C—Cl⋯π, Cl⋯Cl and Cl⋯H inter­actions, forming a three-dimensional network. The Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H⋯H (30.4%), C⋯H/H⋯C (20.4%), Cl⋯H/H⋯Cl (19.4%), Cl⋯Cl (7.8%) and Cl⋯C/C⋯Cl (7.3%) inter­actions. International Union of Crystallography 2021-07-16 /pmc/articles/PMC8340979/ /pubmed/34422307 http://dx.doi.org/10.1107/S2056989021007192 Text en © Shikhaliyev et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Shikhaliyev, Namiq Q.
Atioğlu, Zeliha
Akkurt, Mehmet
Ahmadova, Nigar E.
Askerov, Rizvan K.
Bhattarai, Ajaya
Crystal structure and Hirshfeld surface analysis of 1,3-bis­{2,2-di­chloro-1-[(E)-phenyl­diazen­yl]ethen­yl}benzene
title Crystal structure and Hirshfeld surface analysis of 1,3-bis­{2,2-di­chloro-1-[(E)-phenyl­diazen­yl]ethen­yl}benzene
title_full Crystal structure and Hirshfeld surface analysis of 1,3-bis­{2,2-di­chloro-1-[(E)-phenyl­diazen­yl]ethen­yl}benzene
title_fullStr Crystal structure and Hirshfeld surface analysis of 1,3-bis­{2,2-di­chloro-1-[(E)-phenyl­diazen­yl]ethen­yl}benzene
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of 1,3-bis­{2,2-di­chloro-1-[(E)-phenyl­diazen­yl]ethen­yl}benzene
title_short Crystal structure and Hirshfeld surface analysis of 1,3-bis­{2,2-di­chloro-1-[(E)-phenyl­diazen­yl]ethen­yl}benzene
title_sort crystal structure and hirshfeld surface analysis of 1,3-bis­{2,2-di­chloro-1-[(e)-phenyl­diazen­yl]ethen­yl}benzene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8340979/
https://www.ncbi.nlm.nih.gov/pubmed/34422307
http://dx.doi.org/10.1107/S2056989021007192
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