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Carbon Atom Insertion into Pyrroles and Indoles Promoted by Chlorodiazirines

[Image: see text] Herein, we report a reaction that selectively generates 3-arylpyridine and quinoline motifs by inserting aryl carbynyl cation equivalents into pyrrole and indole cores, respectively. By employing α-chlorodiazirines as thermal precursors to the corresponding chlorocarbenes, the trad...

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Detalles Bibliográficos
Autores principales: Dherange, Balu D., Kelly, Patrick Q., Liles, Jordan P., Sigman, Matthew S., Levin, Mark D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8343525/
https://www.ncbi.nlm.nih.gov/pubmed/34286965
http://dx.doi.org/10.1021/jacs.1c06287