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Carbon Atom Insertion into Pyrroles and Indoles Promoted by Chlorodiazirines
[Image: see text] Herein, we report a reaction that selectively generates 3-arylpyridine and quinoline motifs by inserting aryl carbynyl cation equivalents into pyrrole and indole cores, respectively. By employing α-chlorodiazirines as thermal precursors to the corresponding chlorocarbenes, the trad...
Autores principales: | Dherange, Balu D., Kelly, Patrick Q., Liles, Jordan P., Sigman, Matthew S., Levin, Mark D. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2021
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8343525/ https://www.ncbi.nlm.nih.gov/pubmed/34286965 http://dx.doi.org/10.1021/jacs.1c06287 |
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