Bimodal Evans–Polanyi Relationships in Hydrogen Atom Transfer from C(sp(3))–H Bonds to the Cumyloxyl Radical. A Combined Time-Resolved Kinetic and Computational Study

[Image: see text] The applicability of the Evans–Polanyi (EP) relationship to HAT reactions from C(sp(3))–H bonds to the cumyloxyl radical (CumO(•)) has been investigated. A consistent set of rate constants, k(H), for HAT from the C–H bonds of 56 substrates to CumO(•), spanning a range of more than...

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Detalles Bibliográficos
Autores principales: Salamone, Michela, Galeotti, Marco, Romero-Montalvo, Eduardo, van Santen, Jeffrey A., Groff, Benjamin D., Mayer, James M., DiLabio, Gino A., Bietti, Massimo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8343544/
https://www.ncbi.nlm.nih.gov/pubmed/34309387
http://dx.doi.org/10.1021/jacs.1c05566

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