A dc Method for the Absolute Determination of Conductivities of the Primary Standard KCl Solutions from 0 °C to 50 °C

A new method for the absolute determination of electrolytic conductivity based on direct current and Potentiometric measurements is described. The unique design of the cell uses a removable center section whose length and cross-sectional area are accurately known. Two pairs of matched Ag, AgCl elect...

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Detalles Bibliográficos
Autores principales: Wu, Y. C., Koch, W. F., Feng, D., Holland, L. A., Juhasz, E., Arvay, E., Tomek, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1994
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8345273/
https://www.ncbi.nlm.nih.gov/pubmed/37405080
http://dx.doi.org/10.6028/jres.099.019
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author Wu, Y. C.
Koch, W. F.
Feng, D.
Holland, L. A.
Juhasz, E.
Arvay, E.
Tomek, A.
author_facet Wu, Y. C.
Koch, W. F.
Feng, D.
Holland, L. A.
Juhasz, E.
Arvay, E.
Tomek, A.
author_sort Wu, Y. C.
collection PubMed
description A new method for the absolute determination of electrolytic conductivity based on direct current and Potentiometric measurements is described. The unique design of the cell uses a removable center section whose length and cross-sectional area are accurately known. Two pairs of matched Ag, AgCl electrodes are used in a four terminal mode of resistance measurement. Measurements of the electrolytic conductivity of primary standard potassium chloride solution using [his novel dc conductance cell are compared with the currently adopted IUPAC and OIML recommendations. In addition, measurements have heen made of the electrolytic conductivity of a solution of potassium chloride having a molality of 1 mol/kg (mole KCl per kilogram H(2)O). The values so obtained over the temperature range of 0 °C to 50 °C are recommended as the new primary standards for electrolytic conductivity.
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spelling pubmed-83452732023-07-03 A dc Method for the Absolute Determination of Conductivities of the Primary Standard KCl Solutions from 0 °C to 50 °C Wu, Y. C. Koch, W. F. Feng, D. Holland, L. A. Juhasz, E. Arvay, E. Tomek, A. J Res Natl Inst Stand Technol Article A new method for the absolute determination of electrolytic conductivity based on direct current and Potentiometric measurements is described. The unique design of the cell uses a removable center section whose length and cross-sectional area are accurately known. Two pairs of matched Ag, AgCl electrodes are used in a four terminal mode of resistance measurement. Measurements of the electrolytic conductivity of primary standard potassium chloride solution using [his novel dc conductance cell are compared with the currently adopted IUPAC and OIML recommendations. In addition, measurements have heen made of the electrolytic conductivity of a solution of potassium chloride having a molality of 1 mol/kg (mole KCl per kilogram H(2)O). The values so obtained over the temperature range of 0 °C to 50 °C are recommended as the new primary standards for electrolytic conductivity. [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1994 /pmc/articles/PMC8345273/ /pubmed/37405080 http://dx.doi.org/10.6028/jres.099.019 Text en https://creativecommons.org/publicdomain/zero/1.0/The Journal of Research of the National Institute of Standards and Technology is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright.
spellingShingle Article
Wu, Y. C.
Koch, W. F.
Feng, D.
Holland, L. A.
Juhasz, E.
Arvay, E.
Tomek, A.
A dc Method for the Absolute Determination of Conductivities of the Primary Standard KCl Solutions from 0 °C to 50 °C
title A dc Method for the Absolute Determination of Conductivities of the Primary Standard KCl Solutions from 0 °C to 50 °C
title_full A dc Method for the Absolute Determination of Conductivities of the Primary Standard KCl Solutions from 0 °C to 50 °C
title_fullStr A dc Method for the Absolute Determination of Conductivities of the Primary Standard KCl Solutions from 0 °C to 50 °C
title_full_unstemmed A dc Method for the Absolute Determination of Conductivities of the Primary Standard KCl Solutions from 0 °C to 50 °C
title_short A dc Method for the Absolute Determination of Conductivities of the Primary Standard KCl Solutions from 0 °C to 50 °C
title_sort dc method for the absolute determination of conductivities of the primary standard kcl solutions from 0 °c to 50 °c
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8345273/
https://www.ncbi.nlm.nih.gov/pubmed/37405080
http://dx.doi.org/10.6028/jres.099.019
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