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Infra-Red Active Dirac Plasmon Serie in Potassium Doped-Graphene (KC(8)) Nanoribbons Array on Al(2)O(3) Substrate
A theoretical formulation of the electromagnetic response in graphene ribbons on dielectric substrate is derived in the framework of the ab initio method. The formulation is applied to calculate the electromagnetic energy absorption in an array of potassium-doped graphene nanoribbons (KC [Formula: s...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8347433/ https://www.ncbi.nlm.nih.gov/pubmed/34361450 http://dx.doi.org/10.3390/ma14154256 |
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author | Jakovac, Josip Marušić, Leonardo Andrade-Guevara, Denise Chacón-Torres, Julio C. Despoja, Vito |
author_facet | Jakovac, Josip Marušić, Leonardo Andrade-Guevara, Denise Chacón-Torres, Julio C. Despoja, Vito |
author_sort | Jakovac, Josip |
collection | PubMed |
description | A theoretical formulation of the electromagnetic response in graphene ribbons on dielectric substrate is derived in the framework of the ab initio method. The formulation is applied to calculate the electromagnetic energy absorption in an array of potassium-doped graphene nanoribbons (KC [Formula: see text]-NR) deposited on a dielectric Al [Formula: see text] O [Formula: see text] substrate. It is demonstrated that the replacement of the flat KC [Formula: see text] by an array of KC [Formula: see text]-NR transforms the Drude tail in the absorption spectra into a series of infrared-active Dirac plasmon resonances. It is also shown that the series of Dirac plasmon resonances, when unfolded across the extended Brillouin zones, resembles the Dirac plasmon. The Dirac plasmon resonances’ band structure, within the first Brillouin zone, is calculated. Finally, an excellent agreement between the theoretical absorption and recent experimental results for differential transmission through graphene on an SiO [Formula: see text] /Si surface is presented. The theoretically predicted micrometer graphene nanoribbons intercalation compound (GNRIC) in a stage-I-like KC [Formula: see text] is confirmed to be synthesized for Dirac plasmon resonances. |
format | Online Article Text |
id | pubmed-8347433 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-83474332021-08-08 Infra-Red Active Dirac Plasmon Serie in Potassium Doped-Graphene (KC(8)) Nanoribbons Array on Al(2)O(3) Substrate Jakovac, Josip Marušić, Leonardo Andrade-Guevara, Denise Chacón-Torres, Julio C. Despoja, Vito Materials (Basel) Article A theoretical formulation of the electromagnetic response in graphene ribbons on dielectric substrate is derived in the framework of the ab initio method. The formulation is applied to calculate the electromagnetic energy absorption in an array of potassium-doped graphene nanoribbons (KC [Formula: see text]-NR) deposited on a dielectric Al [Formula: see text] O [Formula: see text] substrate. It is demonstrated that the replacement of the flat KC [Formula: see text] by an array of KC [Formula: see text]-NR transforms the Drude tail in the absorption spectra into a series of infrared-active Dirac plasmon resonances. It is also shown that the series of Dirac plasmon resonances, when unfolded across the extended Brillouin zones, resembles the Dirac plasmon. The Dirac plasmon resonances’ band structure, within the first Brillouin zone, is calculated. Finally, an excellent agreement between the theoretical absorption and recent experimental results for differential transmission through graphene on an SiO [Formula: see text] /Si surface is presented. The theoretically predicted micrometer graphene nanoribbons intercalation compound (GNRIC) in a stage-I-like KC [Formula: see text] is confirmed to be synthesized for Dirac plasmon resonances. MDPI 2021-07-30 /pmc/articles/PMC8347433/ /pubmed/34361450 http://dx.doi.org/10.3390/ma14154256 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Jakovac, Josip Marušić, Leonardo Andrade-Guevara, Denise Chacón-Torres, Julio C. Despoja, Vito Infra-Red Active Dirac Plasmon Serie in Potassium Doped-Graphene (KC(8)) Nanoribbons Array on Al(2)O(3) Substrate |
title | Infra-Red Active Dirac Plasmon Serie in Potassium Doped-Graphene (KC(8)) Nanoribbons Array on Al(2)O(3) Substrate |
title_full | Infra-Red Active Dirac Plasmon Serie in Potassium Doped-Graphene (KC(8)) Nanoribbons Array on Al(2)O(3) Substrate |
title_fullStr | Infra-Red Active Dirac Plasmon Serie in Potassium Doped-Graphene (KC(8)) Nanoribbons Array on Al(2)O(3) Substrate |
title_full_unstemmed | Infra-Red Active Dirac Plasmon Serie in Potassium Doped-Graphene (KC(8)) Nanoribbons Array on Al(2)O(3) Substrate |
title_short | Infra-Red Active Dirac Plasmon Serie in Potassium Doped-Graphene (KC(8)) Nanoribbons Array on Al(2)O(3) Substrate |
title_sort | infra-red active dirac plasmon serie in potassium doped-graphene (kc(8)) nanoribbons array on al(2)o(3) substrate |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8347433/ https://www.ncbi.nlm.nih.gov/pubmed/34361450 http://dx.doi.org/10.3390/ma14154256 |
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