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Facile and Green Synthesis of Starfruit-Like ZIF-L, and Its Optimization Study

Due to its excellent characteristics, zeolitic imidazole framework-L (ZIF-L) is widely used in various applications, such as drug delivery, wastewater treatments and energy storage. In the synthesis of ZIF-L, the molar ratio of ligand to metal, the reaction time and the temperature are essential par...

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Autores principales: Wijaya, Christian J., Ismadji, Suryadi, Aparamarta, Hakun W., Gunawan, Setiyo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8348458/
https://www.ncbi.nlm.nih.gov/pubmed/34361568
http://dx.doi.org/10.3390/molecules26154416
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author Wijaya, Christian J.
Ismadji, Suryadi
Aparamarta, Hakun W.
Gunawan, Setiyo
author_facet Wijaya, Christian J.
Ismadji, Suryadi
Aparamarta, Hakun W.
Gunawan, Setiyo
author_sort Wijaya, Christian J.
collection PubMed
description Due to its excellent characteristics, zeolitic imidazole framework-L (ZIF-L) is widely used in various applications, such as drug delivery, wastewater treatments and energy storage. In the synthesis of ZIF-L, the molar ratio of ligand to metal, the reaction time and the temperature are essential parameters to produce excellent ZIF-L. In this work, ZIF-L was synthesized using a facile and green synthesis method. It was statistically investigated and optimized to obtain the best operating conditions. The optimization was carried out toward the amount of adsorbed crystal violet (CV) dye ([Formula: see text]) as the response in the statistics. The optimal ZIF-L was obtained using a molar ratio of ligand to metal of 8.2220 for 97 min at 29 °C, where the [Formula: see text] value of the CV adsorption onto this optimal ZIF-L reached 823.02 mg/g. The obtained ZIF-L was characterized using SEM, XRD, FTIR and TGA analyses to ensure its excellent characteristics.
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spelling pubmed-83484582021-08-08 Facile and Green Synthesis of Starfruit-Like ZIF-L, and Its Optimization Study Wijaya, Christian J. Ismadji, Suryadi Aparamarta, Hakun W. Gunawan, Setiyo Molecules Article Due to its excellent characteristics, zeolitic imidazole framework-L (ZIF-L) is widely used in various applications, such as drug delivery, wastewater treatments and energy storage. In the synthesis of ZIF-L, the molar ratio of ligand to metal, the reaction time and the temperature are essential parameters to produce excellent ZIF-L. In this work, ZIF-L was synthesized using a facile and green synthesis method. It was statistically investigated and optimized to obtain the best operating conditions. The optimization was carried out toward the amount of adsorbed crystal violet (CV) dye ([Formula: see text]) as the response in the statistics. The optimal ZIF-L was obtained using a molar ratio of ligand to metal of 8.2220 for 97 min at 29 °C, where the [Formula: see text] value of the CV adsorption onto this optimal ZIF-L reached 823.02 mg/g. The obtained ZIF-L was characterized using SEM, XRD, FTIR and TGA analyses to ensure its excellent characteristics. MDPI 2021-07-21 /pmc/articles/PMC8348458/ /pubmed/34361568 http://dx.doi.org/10.3390/molecules26154416 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Wijaya, Christian J.
Ismadji, Suryadi
Aparamarta, Hakun W.
Gunawan, Setiyo
Facile and Green Synthesis of Starfruit-Like ZIF-L, and Its Optimization Study
title Facile and Green Synthesis of Starfruit-Like ZIF-L, and Its Optimization Study
title_full Facile and Green Synthesis of Starfruit-Like ZIF-L, and Its Optimization Study
title_fullStr Facile and Green Synthesis of Starfruit-Like ZIF-L, and Its Optimization Study
title_full_unstemmed Facile and Green Synthesis of Starfruit-Like ZIF-L, and Its Optimization Study
title_short Facile and Green Synthesis of Starfruit-Like ZIF-L, and Its Optimization Study
title_sort facile and green synthesis of starfruit-like zif-l, and its optimization study
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8348458/
https://www.ncbi.nlm.nih.gov/pubmed/34361568
http://dx.doi.org/10.3390/molecules26154416
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