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Evidence for ligand- and solvent-induced disproportionation of uranium(IV)

Disproportionation, where a chemical element converts its oxidation state to two different ones, one higher and one lower, underpins the fundamental chemistry of metal ions. The overwhelming majority of uranium disproportionations involve uranium(III) and (V), with a singular example of uranium(IV)...

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Detalles Bibliográficos
Autores principales: Du, Jingzhen, Douair, Iskander, Lu, Erli, Seed, John A., Tuna, Floriana, Wooles, Ashley J., Maron, Laurent, Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8355312/
https://www.ncbi.nlm.nih.gov/pubmed/34376682
http://dx.doi.org/10.1038/s41467-021-25151-z