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Illuminating anti-hydrozirconation: controlled geometric isomerization of an organometallic species

A general strategy to enable the formal anti-hydrozirconation of arylacetylenes is reported that merges cis-hydrometallation using the Schwartz Reagent (Cp(2)ZrHCl) with a subsequent light-mediated geometric isomerization at λ = 400 nm. Mechanistic delineation of the contra-thermodynamic isomerizati...

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Detalles Bibliográficos
Autores principales:	Hostmann, Theresa, Neveselý, Tomáš, Gilmour, Ryan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8356810/ https://www.ncbi.nlm.nih.gov/pubmed/34447557 http://dx.doi.org/10.1039/d1sc02454j

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