Asymmetric Allylation Catalyzed by Chiral Phosphoric Acids: Stereoselective Synthesis of Tertiary Alcohols and a Reagent‐Based Switch in Stereopreference

The substrate scope of the asymmetric allylation with zinc organyls catalyzed by 3,3‐bis(2,4,6‐triisopropylphenyl)‐1,1‐binaphthyl‐2,2‐diyl hydrogenphosphate (TRIP) has been extended to non‐cyclic ester organozinc reagents and ketones. Tertiary chiral alcohols are obtained with ee's up to 94% an...

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Detalles Bibliográficos
Autores principales: Lazzarotto, Mattia, Hartmann, Peter, Pletz, Jakob, Belaj, Ferdinand, Kroutil, Wolfgang, Payer, Stefan E., Fuchs, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Updates
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8359974/
https://www.ncbi.nlm.nih.gov/pubmed/34413715
http://dx.doi.org/10.1002/adsc.202100037

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8359974/
https://www.ncbi.nlm.nih.gov/pubmed/34413715
http://dx.doi.org/10.1002/adsc.202100037

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