Cationic Heterobimetallic Mg(Zn)/Al(Ga) Combinations for Cooperative C–F Bond Cleavage

Low‐valent ((Me)BDI)Al and ((Me)BDI)Ga and highly Lewis acidic cations in [((tBu)BDI)M(+)⋅C(6)H(6)][(B(C(6)F(5))(4) (−)] (M=Mg or Zn, (Me)BDI=HC[C(Me)N‐DIPP](2), (tBu)BDI=HC[C(tBu)N‐DIPP](2), DIPP=2,6‐diisopropylphenyl) react to heterobimetallic cations [((tBu)BDI)Mg–Al((Me)BDI)(+)], [((tBu)BDI)Mg–G...

Descripción completa

Detalles Bibliográficos
Autores principales: Friedrich, Alexander, Eyselein, Jonathan, Langer, Jens, Färber, Christian, Harder, Sjoerd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8361950/
https://www.ncbi.nlm.nih.gov/pubmed/33979476
http://dx.doi.org/10.1002/anie.202103250

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8361950/
https://www.ncbi.nlm.nih.gov/pubmed/33979476
http://dx.doi.org/10.1002/anie.202103250

Ejemplares similares