Cargando…
Cationic Heterobimetallic Mg(Zn)/Al(Ga) Combinations for Cooperative C–F Bond Cleavage
Low‐valent ((Me)BDI)Al and ((Me)BDI)Ga and highly Lewis acidic cations in [((tBu)BDI)M(+)⋅C(6)H(6)][(B(C(6)F(5))(4) (−)] (M=Mg or Zn, (Me)BDI=HC[C(Me)N‐DIPP](2), (tBu)BDI=HC[C(tBu)N‐DIPP](2), DIPP=2,6‐diisopropylphenyl) react to heterobimetallic cations [((tBu)BDI)Mg–Al((Me)BDI)(+)], [((tBu)BDI)Mg–G...
Autores principales: | Friedrich, Alexander, Eyselein, Jonathan, Langer, Jens, Färber, Christian, Harder, Sjoerd |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8361950/ https://www.ncbi.nlm.nih.gov/pubmed/33979476 http://dx.doi.org/10.1002/anie.202103250 |
Ejemplares similares
-
Cationic Aluminium Complexes as Catalysts for Imine Hydrogenation
por: Friedrich, Alexander, et al.
Publicado: (2021) -
Bonding and Reactivity of a Pair of Neutral and Cationic
Heterobimetallic RuZn(2) Complexes
por: Miloserdov, Fedor M., et al.
Publicado: (2021) -
Unsupported Mg–Alkene Bonding
por: Thum, Katharina, et al.
Publicado: (2020) -
Boosting Low‐Valent Aluminum(I) Reactivity with a Potassium Reagent
por: Grams, Samuel, et al.
Publicado: (2020) -
Magnesium–halobenzene bonding: mapping the halogen sigma-hole with a Lewis-acidic complex
por: Friedrich, Alexander, et al.
Publicado: (2020)