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1,2‐ or 1,3‐Hydride Shifts: What Controls Guaiane Biosynthesis?
A systematic computational study addressing the entire chemical space of guaianes in conjunction with an analysis of all known compounds shows that 1,3‐hydride shifts are rare events in guaiane biosynthesis. As demonstrated here, 1,3‐hydride shifts towards guaianes can only be realized for two stere...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362104/ https://www.ncbi.nlm.nih.gov/pubmed/33929065 http://dx.doi.org/10.1002/chem.202101371 |