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Hydrosilane σ‐Adduct Intermediates in an Adaptive Zinc‐Catalyzed Cross‐dehydrocoupling of Si−H and O−H Bonds

Three‐coordinate (Ph)BOX [Formula: see text] ZnR ((Ph)BOX [Formula: see text] =phenyl‐(4,4‐dimethyl‐oxazolinato; R=Me: 2 a, Et: 2 b) catalyzes the dehydrocoupling of primary or secondary silanes and alcohols to give silyl ethers and hydrogen, with high turnover numbers (TON; up to 10(7)) under solve...

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Detalles Bibliográficos
Autores principales: Patnaik, Smita, Kanbur, Uddhav, Ellern, Arkady, Sadow, Aaron D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362191/
https://www.ncbi.nlm.nih.gov/pubmed/33876468
http://dx.doi.org/10.1002/chem.202101146