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Hydrosilane σ‐Adduct Intermediates in an Adaptive Zinc‐Catalyzed Cross‐dehydrocoupling of Si−H and O−H Bonds
Three‐coordinate (Ph)BOX [Formula: see text] ZnR ((Ph)BOX [Formula: see text] =phenyl‐(4,4‐dimethyl‐oxazolinato; R=Me: 2 a, Et: 2 b) catalyzes the dehydrocoupling of primary or secondary silanes and alcohols to give silyl ethers and hydrogen, with high turnover numbers (TON; up to 10(7)) under solve...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362191/ https://www.ncbi.nlm.nih.gov/pubmed/33876468 http://dx.doi.org/10.1002/chem.202101146 |