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A Pair of Cobalt(III/IV) Terminal Imido Complexes

The reaction of the cobalt(I) complex [(TIMMN(mes))Co(I)](BPh(4)) (2) (TIMMN(mes)=tris‐[2‐(3‐mesitylimidazolin‐2‐ylidene)methyl]amine) with 1‐adamantylazide yields the cobalt(III) imido complex [(TIMMN(mes))Co(III)(NAd)](BPh(4)) (3) with concomitant release of dinitrogen. The N‐anchor in diamagnetic...

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Detalles Bibliográficos
Autores principales:	Mao, Weiqing, Fehn, Dominik, Heinemann, Frank W., Scheurer, Andreas, Munz, Dominik, Meyer, Karsten
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362208/ https://www.ncbi.nlm.nih.gov/pubmed/33847448 http://dx.doi.org/10.1002/anie.202103170

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