Cargando…
Optimization of crystal packing in semiconducting spin-crossover materials with fractionally charged TCNQ(δ−) anions (0 < δ < 1)
Co-crystallization of the prominent Fe(ii) spin-crossover (SCO) cation, [Fe(3-bpp)(2)](2+) (3-bpp = 2,6-bis(pyrazol-3-yl)pyridine), with a fractionally charged TCNQ(δ−) radical anion has afforded a hybrid complex [Fe(3-bpp)(2)](TCNQ)(3)·5MeCN (1·5MeCN, where δ = −0.67). The partially desolvated mate...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8372557/ https://www.ncbi.nlm.nih.gov/pubmed/34476058 http://dx.doi.org/10.1039/d1sc02843j |