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Which is the best (9)Be carrier for (10)Be/(9)Be accelerator mass spectrometry?

Commercial (9)Be solutions used for chemical preparation of samples for accelerator mass spectrometry contain the cosmogenic long-lived radionuclide (10)Be at elevated but different (10)Be/(9)Be levels. Within a systematic study of recently produced solutions, comparison to published data and new da...

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Detalles Bibliográficos
Autores principales: Merchel, Silke, Braucher, Régis, Lachner, Johannes, Rugel, Georg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8374718/
https://www.ncbi.nlm.nih.gov/pubmed/34434884
http://dx.doi.org/10.1016/j.mex.2021.101486
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author Merchel, Silke
Braucher, Régis
Lachner, Johannes
Rugel, Georg
author_facet Merchel, Silke
Braucher, Régis
Lachner, Johannes
Rugel, Georg
author_sort Merchel, Silke
collection PubMed
description Commercial (9)Be solutions used for chemical preparation of samples for accelerator mass spectrometry contain the cosmogenic long-lived radionuclide (10)Be at elevated but different (10)Be/(9)Be levels. Within a systematic study of recently produced solutions, comparison to published data and new data on customised solutions from minerals, we recommend - if no customised solution is available - the (9)Be solutions from Australian Chemical Reagents (ACR) or from LGC. They contain (10)Be/(9)Be at the 3.4 × 10(−15) level, which is still suitable for the majority of Earth science applications, compared to customised solutions at the 10(−16) level for lowest-level studies. Commercial solutions from Scharlab having different lot numbers, i.e. an identification number assigned to a particular lot of material from a single manufacturer, vary in (10)Be/(9)Be by up to a factor of nine. Hence, it seems an advisable strategy to buy a bigger quantity of a single production batch (such as 10 × 100 ml bottles of (9)Be at 1 g l(−1)) and have them tested once at any AMS facility before first use. • The best (9)Be carrier for low-level (10)Be/(9)Be applications is a customised one from minerals like phenakite. • The best (9)Be carriers for medium- and high-level (10)Be/(9)Be applications are currently from Australian Chemical Reagents (ACR) or from LGC. • As (9)Be carriers from Scharlab of different batches (LOT) contain (10)Be/(9)Be at different levels, it is advisable to buy a bigger number of bottles of the same LOT of commercial carriers after being identified to have reasonably low isotope ratios.
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spelling pubmed-83747182021-08-24 Which is the best (9)Be carrier for (10)Be/(9)Be accelerator mass spectrometry? Merchel, Silke Braucher, Régis Lachner, Johannes Rugel, Georg MethodsX Method Article Commercial (9)Be solutions used for chemical preparation of samples for accelerator mass spectrometry contain the cosmogenic long-lived radionuclide (10)Be at elevated but different (10)Be/(9)Be levels. Within a systematic study of recently produced solutions, comparison to published data and new data on customised solutions from minerals, we recommend - if no customised solution is available - the (9)Be solutions from Australian Chemical Reagents (ACR) or from LGC. They contain (10)Be/(9)Be at the 3.4 × 10(−15) level, which is still suitable for the majority of Earth science applications, compared to customised solutions at the 10(−16) level for lowest-level studies. Commercial solutions from Scharlab having different lot numbers, i.e. an identification number assigned to a particular lot of material from a single manufacturer, vary in (10)Be/(9)Be by up to a factor of nine. Hence, it seems an advisable strategy to buy a bigger quantity of a single production batch (such as 10 × 100 ml bottles of (9)Be at 1 g l(−1)) and have them tested once at any AMS facility before first use. • The best (9)Be carrier for low-level (10)Be/(9)Be applications is a customised one from minerals like phenakite. • The best (9)Be carriers for medium- and high-level (10)Be/(9)Be applications are currently from Australian Chemical Reagents (ACR) or from LGC. • As (9)Be carriers from Scharlab of different batches (LOT) contain (10)Be/(9)Be at different levels, it is advisable to buy a bigger number of bottles of the same LOT of commercial carriers after being identified to have reasonably low isotope ratios. Elsevier 2021-08-11 /pmc/articles/PMC8374718/ /pubmed/34434884 http://dx.doi.org/10.1016/j.mex.2021.101486 Text en © 2021 The Authors. Published by Elsevier B.V. https://creativecommons.org/licenses/by/4.0/This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Method Article
Merchel, Silke
Braucher, Régis
Lachner, Johannes
Rugel, Georg
Which is the best (9)Be carrier for (10)Be/(9)Be accelerator mass spectrometry?
title Which is the best (9)Be carrier for (10)Be/(9)Be accelerator mass spectrometry?
title_full Which is the best (9)Be carrier for (10)Be/(9)Be accelerator mass spectrometry?
title_fullStr Which is the best (9)Be carrier for (10)Be/(9)Be accelerator mass spectrometry?
title_full_unstemmed Which is the best (9)Be carrier for (10)Be/(9)Be accelerator mass spectrometry?
title_short Which is the best (9)Be carrier for (10)Be/(9)Be accelerator mass spectrometry?
title_sort which is the best (9)be carrier for (10)be/(9)be accelerator mass spectrometry?
topic Method Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8374718/
https://www.ncbi.nlm.nih.gov/pubmed/34434884
http://dx.doi.org/10.1016/j.mex.2021.101486
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