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Chemoselective Ullmann Reaction of α-Trisubstituted Thioamides: Synthesis of Novel 2-Iminobenzothiolanes

[Image: see text] New classes of unexplored benzo[b]thiolanes are synthesized from trisubstituted thioamides through copper-catalyzed intramolecular S-arylation of thioamides for the first time. This method provides good to excellent yields with fully controlled chemoselectivity. Unusually, iminoben...

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Detalles Bibliográficos
Autores principales: Bhattacharya, Anwesha, Thirupathi, Annaram, Natarajan, Pradeep, Peruncheralathan, Saravanan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8375098/
https://www.ncbi.nlm.nih.gov/pubmed/34423225
http://dx.doi.org/10.1021/acsomega.1c03410