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Triple Resonance Experiments for the Rapid Detection of (103)Rh NMR Shifts: A Combined Experimental and Theoretical Study into Dirhodium and Bismuth–Rhodium Paddlewheel Complexes

[Image: see text] A H(C)Rh triple resonance NMR experiment makes the rapid detection of (103)Rh chemical shifts possible, which were previously beyond reach. It served to analyze a series of dirhodium and bismuth–rhodium paddlewheel complexes of the utmost importance for metal–carbene chemistry. The...

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Detalles Bibliográficos
Autores principales: Caló, Fabio P., Bistoni, Giovanni, Auer, Alexander A., Leutzsch, Markus, Fürstner, Alois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8377716/
https://www.ncbi.nlm.nih.gov/pubmed/34351134
http://dx.doi.org/10.1021/jacs.1c06414