Bis(2-methyl­pyridinium) tetra­chlorido­cuprate(II): synthesis, structure and Hirshfeld surface analysis

The title compound, (C(6)H(8)N)(2)[CuCl(4)], crystallizes in the monoclinic space group I2/c. The coordination around the copper atom is a distorted tetra­hedron. The 2-methyl­pyridinium ion (C(6)H(8)N(+)) inter­acts with the tetra­chloro­cuprate anion through N—H⋯Cl and C—H(phen­yl)⋯Cl contacts, fo...

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Detalles Bibliográficos
Autores principales: Mehmood, Tahir, Bhosale, Rajesh S., Reddy, J. Prakasha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8382058/
https://www.ncbi.nlm.nih.gov/pubmed/34513019
http://dx.doi.org/10.1107/S2056989021006277
Descripción
Sumario:The title compound, (C(6)H(8)N)(2)[CuCl(4)], crystallizes in the monoclinic space group I2/c. The coordination around the copper atom is a distorted tetra­hedron. The 2-methyl­pyridinium ion (C(6)H(8)N(+)) inter­acts with the tetra­chloro­cuprate anion through N—H⋯Cl and C—H(phen­yl)⋯Cl contacts, forming a hydrogen-bonded layer-like structure. The supra­molecular structure is further stabilized by C—H(meth­yl)⋯Cl inter­actions between the layers.

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