Bis(2-methyl­pyridinium) tetra­chlorido­cuprate(II): synthesis, structure and Hirshfeld surface analysis

The title compound, (C(6)H(8)N)(2)[CuCl(4)], crystallizes in the monoclinic space group I2/c. The coordination around the copper atom is a distorted tetra­hedron. The 2-methyl­pyridinium ion (C(6)H(8)N(+)) inter­acts with the tetra­chloro­cuprate anion through N—H⋯Cl and C—H(phen­yl)⋯Cl contacts, fo...

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Detalles Bibliográficos
Autores principales: Mehmood, Tahir, Bhosale, Rajesh S., Reddy, J. Prakasha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8382058/
https://www.ncbi.nlm.nih.gov/pubmed/34513019
http://dx.doi.org/10.1107/S2056989021006277
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author Mehmood, Tahir
Bhosale, Rajesh S.
Reddy, J. Prakasha
author_facet Mehmood, Tahir
Bhosale, Rajesh S.
Reddy, J. Prakasha
author_sort Mehmood, Tahir
collection PubMed
description The title compound, (C(6)H(8)N)(2)[CuCl(4)], crystallizes in the monoclinic space group I2/c. The coordination around the copper atom is a distorted tetra­hedron. The 2-methyl­pyridinium ion (C(6)H(8)N(+)) inter­acts with the tetra­chloro­cuprate anion through N—H⋯Cl and C—H(phen­yl)⋯Cl contacts, forming a hydrogen-bonded layer-like structure. The supra­molecular structure is further stabilized by C—H(meth­yl)⋯Cl inter­actions between the layers.
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spelling pubmed-83820582021-09-09 Bis(2-methyl­pyridinium) tetra­chlorido­cuprate(II): synthesis, structure and Hirshfeld surface analysis Mehmood, Tahir Bhosale, Rajesh S. Reddy, J. Prakasha Acta Crystallogr E Crystallogr Commun Research Communications The title compound, (C(6)H(8)N)(2)[CuCl(4)], crystallizes in the monoclinic space group I2/c. The coordination around the copper atom is a distorted tetra­hedron. The 2-methyl­pyridinium ion (C(6)H(8)N(+)) inter­acts with the tetra­chloro­cuprate anion through N—H⋯Cl and C—H(phen­yl)⋯Cl contacts, forming a hydrogen-bonded layer-like structure. The supra­molecular structure is further stabilized by C—H(meth­yl)⋯Cl inter­actions between the layers. International Union of Crystallography 2021-06-25 /pmc/articles/PMC8382058/ /pubmed/34513019 http://dx.doi.org/10.1107/S2056989021006277 Text en © Mehmood et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Mehmood, Tahir
Bhosale, Rajesh S.
Reddy, J. Prakasha
Bis(2-methyl­pyridinium) tetra­chlorido­cuprate(II): synthesis, structure and Hirshfeld surface analysis
title Bis(2-methyl­pyridinium) tetra­chlorido­cuprate(II): synthesis, structure and Hirshfeld surface analysis
title_full Bis(2-methyl­pyridinium) tetra­chlorido­cuprate(II): synthesis, structure and Hirshfeld surface analysis
title_fullStr Bis(2-methyl­pyridinium) tetra­chlorido­cuprate(II): synthesis, structure and Hirshfeld surface analysis
title_full_unstemmed Bis(2-methyl­pyridinium) tetra­chlorido­cuprate(II): synthesis, structure and Hirshfeld surface analysis
title_short Bis(2-methyl­pyridinium) tetra­chlorido­cuprate(II): synthesis, structure and Hirshfeld surface analysis
title_sort bis(2-methyl­pyridinium) tetra­chlorido­cuprate(ii): synthesis, structure and hirshfeld surface analysis
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8382058/
https://www.ncbi.nlm.nih.gov/pubmed/34513019
http://dx.doi.org/10.1107/S2056989021006277
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