Intercalates of Bi(2)Se(3) studied in situ by time-resolved powder X-ray diffraction and neutron diffraction

Intercalation of lithium and ammonia into the layered semiconductor Bi(2)Se(3) proceeds via a hyperextended (by >60%) ammonia-rich intercalate, to eventually produce a layered compound with lithium amide intercalated between the bismuth selenide layers which offers scope for further chemical mani...

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Detalles Bibliográficos
Autores principales: Kamminga, Machteld E., Cassidy, Simon J., Jana, Partha P., Elgaml, Mahmoud, Kelly, Nicola D., Clarke, Simon J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8383151/
https://www.ncbi.nlm.nih.gov/pubmed/34397063
http://dx.doi.org/10.1039/d1dt00960e
Descripción
Sumario:Intercalation of lithium and ammonia into the layered semiconductor Bi(2)Se(3) proceeds via a hyperextended (by >60%) ammonia-rich intercalate, to eventually produce a layered compound with lithium amide intercalated between the bismuth selenide layers which offers scope for further chemical manipulation.

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