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Manganese-Pincer-Catalyzed Nitrile Hydration, α-Deuteration, and α-Deuterated Amide Formation via Metal Ligand Cooperation

[Image: see text] A simple and efficient system for the hydration and α-deuteration of nitriles to form amides, α-deuterated nitriles, and α-deuterated amides catalyzed by a single pincer complex of the earth-abundant manganese capable of metal–ligand cooperation is reported. The reaction is selecti...

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Detalles Bibliográficos
Autores principales:	Zhou, Quan-Quan, Zou, You-Quan, Kar, Sayan, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8383274/ https://www.ncbi.nlm.nih.gov/pubmed/34476112 http://dx.doi.org/10.1021/acscatal.1c01748

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