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Electrostatic Potential Field Effects on Amine Macrocyclizations within Yoctoliter Spaces: Supramolecular Electron Withdrawing/Donating Groups

[Image: see text] The central role of Coulombic interactions in enzyme catalysis has inspired multiple approaches to sculpting electrostatic potential fields (EPFs) for controlling chemical reactivity, including ion gradients in water microdroplets, the tips of STMs, and precisely engineered crystal...

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Detalles Bibliográficos
Autores principales: Yao, Wei, Wang, Kaiyu, Ismaiel, Yahya A., Wang, Ruiqing, Cai, Xiaoyang, Teeler, Mary, Gibb, Bruce C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8383300/
https://www.ncbi.nlm.nih.gov/pubmed/34355901
http://dx.doi.org/10.1021/acs.jpcb.1c05238

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