Cargando…
Controlling Radical-Type Single-Electron Elementary Steps in Catalysis with Redox-Active Ligands and Substrates
[Image: see text] Advances in (spectroscopic) characterization of the unusual electronic structures of open-shell cobalt complexes bearing redox-active ligands, combined with detailed mapping of their reactivity, have uncovered several new catalytic radical-type protocols that make efficient use of...
Autores principales: | van Leest, Nicolaas P., de Zwart, Felix J., Zhou, Minghui, de Bruin, Bas |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2021
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8385710/ https://www.ncbi.nlm.nih.gov/pubmed/34467352 http://dx.doi.org/10.1021/jacsau.1c00224 |
Ejemplares similares
-
Electronically Asynchronous Transition States for
C–N Bond Formation by Electrophilic [Co(III)(TAML)]-Nitrene Radical Complexes Involving Substrate-to-Ligand
Single-Electron Transfer and a Cobalt-Centered Spin Shuttle
por: van Leest, Nicolaas P., et al.
Publicado: (2020) -
Revisiting the Electronic Structure of Cobalt Porphyrin Nitrene and Carbene Radicals with
NEVPT2-CASSCF Calculations: Doublet versus Quartet Ground States
por: van Leest, Nicolaas P., et al.
Publicado: (2021) -
Radical‐Type Reactivity and Catalysis by Single‐Electron Transfer to or from Redox‐Active Ligands
por: van der Vlugt, Jarl Ivar
Publicado: (2018) -
Ligand Redox Noninnocence
in [Co(III)(TAML)](0/–) Complexes Affects
Nitrene Formation
por: van Leest, Nicolaas P., et al.
Publicado: (2019) -
Catalytic Chemoselective Sulfimidation with an Electrophilic [Co(III)(TAML)](−)‐Nitrene Radical Complex
por: van Leest, Nicolaas P., et al.
Publicado: (2020)