Cargando…
Lewis acid catalyzed heavy atom tunneling – the case of 1H-bicyclo[3.1.0]-hexa-3,5-dien-2-one
For many thermal reactions, the effects of catalysis or the influence of solvents on reaction rates can be rationalized by simple transition state models. This is not the case for reactions controlled by quantum tunneling, which do not proceed via transition states, and therefore lack the simple con...
Autores principales: | Henkel, Stefan, Merini, Melania Prado, Mendez-Vega, Enrique, Sander, Wolfram |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8386641/ https://www.ncbi.nlm.nih.gov/pubmed/34522298 http://dx.doi.org/10.1039/d1sc02853g |
Ejemplares similares
-
Synthesis of bicyclo[3.1.0]hexanes by (3 + 2) annulation of cyclopropenes with aminocyclopropanes
por: Muriel, Bastian, et al.
Publicado: (2019) -
The Mystery of the Benzene‐Oxide/Oxepin Equilibrium—Heavy‐Atom Tunneling Reversed by Solvent Interactions
por: Schleif, Tim, et al.
Publicado: (2020) -
(1S,5R)-1-(4-Fluorophenyl)-3-azoniabicyclo[3.1.0]hexane chloride
por: Görbitz, Carl Henrik, et al.
Publicado: (2009) -
Synthesis of enantiomerically pure d- and l-bicyclo[3.1.0]hexenyl carbanucleosides and their antiviral evaluation
por: Park, Ah-Young, et al.
Publicado: (2011) -
Biological Evaluation of 3-Azaspiro[Bicyclo[3.1.0]Hexane-2,5′-Pyrimidines] as Potential Antitumor Agents
por: Shmakov, Stanislav V., et al.
Publicado: (2022)