Cargando…

Organocatalytic asymmetric synthesis of α-amino esters from sulfoxonium ylides

Described here is the first organocatalytic asymmetric N–H insertion reaction of α-carbonyl sulfoxonium ylides. Without a metal catalyst, this reaction represents an attractive complement to the well-established carbene insertion reactions. As a stable surrogate of diazocarbonyl compounds, sulfoxoni...

Descripción completa

Detalles Bibliográficos
Autores principales:	Guo, Wengang, Wang, Min, Han, Zhengyu, Huang, Hai, Sun, Jianwei
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8386753/ https://www.ncbi.nlm.nih.gov/pubmed/34522316 http://dx.doi.org/10.1039/d1sc02439f

Ejemplares similares

Organocatalytic asymmetric azidation of sulfoxonium ylides: mild synthesis of enantioenriched α-azido ketones bearing a labile tertiary stereocenter
por: Guo, Wengang, et al.
Publicado: (2022)

Asymmetric transformations from sulfoxonium ylides
por: Caiuby, Clarice A. D., et al.
Publicado: (2021)

Correction: Dearomatization of benzopyrylium triflates with sulfoxonium ylides
por: Leveille, Alexandria N., et al.
Publicado: (2023)

The thiol-sulfoxonium ylide photo-click reaction for bioconjugation
por: Wan, Chuan, et al.
Publicado: (2022)

Rhodium(iii)-catalyzed annulation of enamides with sulfoxonium ylides toward isoquinolines
por: Hong, Chao, et al.
Publicado: (2021)

Enantioselective S−H Insertion Reactions of α‐Carbonyl Sulfoxonium Ylides
por: Momo, Patrícia B., et al.
Publicado: (2020)

Chemospecific Cyclizations of α‐Carbonyl Sulfoxonium Ylides on Aryls and Heteroaryls
por: Clare, Daniel, et al.
Publicado: (2019)

Enantioselective Intramolecular Iridium-Catalyzed Cyclopropanation of α-Carbonyl Sulfoxonium Ylides
por: Vidal, Lucas, et al.
Publicado: (2022)

Cooperative copper-squaramide catalysis for the enantioselective N–H insertion reaction with sulfoxonium ylides
por: Furniel, Lucas G., et al.
Publicado: (2021)

Rhodium(iii)-catalyzed C–H annulation of 2-acetyl-1-arylhydrazines with sulfoxonium ylides: synthesis of 2-arylindoles
por: Li, He, et al.
Publicado: (2020)

Visible-light-induced organocatalytic enantioselective N–H insertion of α-diazoesters enabled by indirect free carbene capture
por: Guo, Wengang, et al.
Publicado: (2022)

Ruthenium(II)-Catalyzed Homocoupling of α-Carbonyl Sulfoxonium Ylides Under Mild Conditions: Methodology Development and Mechanistic DFT Study
por: Zhang, Maosheng, et al.
Publicado: (2020)

A Catalytic Cross‐Olefination of Diazo Compounds with Sulfoxonium Ylides
por: Neuhaus, James D., et al.
Publicado: (2018)

Regioselective α-addition of vinylogous α-ketoester enolate in organocatalytic asymmetric Michael reactions: enantioselective synthesis of Rauhut–Currier type products
por: Weng, Zhibing, et al.
Publicado: (2022)

Organocatalytic asymmetric synthesis of P-stereogenic molecules
por: Liu, Junyang, et al.
Publicado: (2023)

Sulfoxonium Ylides in Aminocatalysis: An Enantioselective Entry to Cyclopropane-Fused Chromanol Structures
por: Bisag, Giorgiana Denisa, et al.
Publicado: (2022)

Ru(ii)-catalyzed C6-selective C–H acylmethylation of pyridones using sulfoxonium ylides as carbene precursors
por: Fu, Yangjie, et al.
Publicado: (2020)

Ruthenium(ii)-catalyzed chemoselective deacylative annulation of 1,3-diones with sulfoxonium ylides via C–C bond activation
por: Wen, Si, et al.
Publicado: (2019)

Organocatalytic asymmetric chlorinative dearomatization of naphthols
por: Yin, Qin, et al.
Publicado: (2015)

Insights into the Activation Mode of α‐Carbonyl Sulfoxonium Ylides in Rhodium‐Catalyzed C−H Activation: A Theoretical Study
por: Zhang, Dianmin, et al.
Publicado: (2022)

Rhodium(III)-Catalyzed [4+2] Annulation via C-H Activation: Synthesis of Multi-Substituted Naphthalenone Sulfoxonium Ylides
por: Song, Xiaohan, et al.
Publicado: (2019)

Terpolymers from Borane‐Initiated Copolymerization of Triphenyl Arsonium and Sulfoxonium Ylides: An Unexpected Light Emission
por: Wang, De, et al.
Publicado: (2019)

Organocatalytic asymmetric formal oxidative coupling for the construction of all-aryl quaternary stereocenters
por: Li, Zhiyang, et al.
Publicado: (2021)

Enantioselective organocatalytic syntheses of α-selenated α- and β-amino acid derivatives
por: Haider, Victoria, et al.
Publicado: (2022)

Asymmetric synthesis of isochromanone derivatives via trapping carboxylic oxonium ylides and aldol cascade
por: Lang, Jiawen, et al.
Publicado: (2021)

Asymmetric synthesis of chiral 1,2-oxazinane and hexahydropyridazin spirocyclic scaffolds by organocatalytic [4 + 2] cycloaddition
por: Tian, Heng-Zhi, et al.
Publicado: (2022)

Synthesis of chiral N-phosphinyl α-imino esters and their application in asymmetric synthesis of α-amino esters by reduction
por: Xiong, Yiwen, et al.
Publicado: (2014)

Asymmetric synthesis of N–N axially chiral compounds via organocatalytic atroposelective N-acylation
por: Lin, Wei, et al.
Publicado: (2021)

Organocatalytic chiral polymeric nanoparticles for asymmetric aldol reaction
por: Abuaf, Meir, et al.
Publicado: (2023)

The synthesis of pharmacologically important oxindoles via the asymmetric aldol reaction of isatin and the investigation of the organocatalytic activity of new alicyclic β-amino acid derivatives
por: Faragó, Tünde, et al.
Publicado: (2023)

Absolute and relative facial selectivities in organocatalytic asymmetric chlorocyclization reactions
por: Salehi Marzijarani, Nastaran, et al.
Publicado: (2018)

Direct β-selectivity of α,β-unsaturated γ-butyrolactam for asymmetric conjugate additions in an organocatalytic manner
por: Zhong, Yuan, et al.
Publicado: (2018)

Asymmetric Mannich Synthesis of α-Amino Esters by Anion-Binding Catalysis
por: Wasa, Masayuki, et al.
Publicado: (2014)

Asymmetric synthesis of polysubstituted chiral chromans via an organocatalytic oxa-Michael-nitro-Michael domino reaction
por: Tang, Cheng-Ke, et al.
Publicado: (2018)

Synthesis of polysubstituted arenes through organocatalytic benzannulation
por: Zhao, Qian, et al.
Publicado: (2020)

Organocatalytic Asymmetric Synthesis of Si-Stereogenic Silyl Ethers
por: Zhou, Hui, et al.
Publicado: (2022)

Synthesis of bioactive fluoropyrrolidines via copper(i)-catalysed asymmetric 1,3-dipolar cycloaddition of azomethine ylides
por: Xu, Xiao, et al.
Publicado: (2021)

Recent approaches in the organocatalytic synthesis of pyrroles
por: Borah, Biplob, et al.
Publicado: (2021)

Towards an asymmetric organocatalytic α-cyanation of β-ketoesters
por: Chowdhury, Raghunath, et al.
Publicado: (2015)

Towards an Asymmetric Organocatalytic α-Azidation of β-Ketoesters
por: Tiffner, Maximilian, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_02q8gph0se8dpa6gp7hnhofru8