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Unpredicted but It Exists: Trigonal Sc(2)Ru with a Significant Metal–Metal Charge Transfer

[Image: see text] The Sc(2)Ru compound, obtained by high-temperature synthesis, was found to crystallize in a new trigonal hP45 structure type [space group P3̅m1; a = 9.3583(9) Å and c = 11.285(1) Å]: Ru@Sc(8) cubes, Ru@Sc(12) icosahedra, and uncommon Ru@Sc(10) sphenocoronae are the building blocks...

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Detalles Bibliográficos
Autores principales: Freccero, Riccardo, Solokha, Pavlo, De Negri, Serena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8389775/
https://www.ncbi.nlm.nih.gov/pubmed/34240596
http://dx.doi.org/10.1021/acs.inorgchem.1c01168