Cargando…
Unpredicted but It Exists: Trigonal Sc(2)Ru with a Significant Metal–Metal Charge Transfer
[Image: see text] The Sc(2)Ru compound, obtained by high-temperature synthesis, was found to crystallize in a new trigonal hP45 structure type [space group P3̅m1; a = 9.3583(9) Å and c = 11.285(1) Å]: Ru@Sc(8) cubes, Ru@Sc(12) icosahedra, and uncommon Ru@Sc(10) sphenocoronae are the building blocks...
Autores principales: | Freccero, Riccardo, Solokha, Pavlo, De Negri, Serena |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8389775/ https://www.ncbi.nlm.nih.gov/pubmed/34240596 http://dx.doi.org/10.1021/acs.inorgchem.1c01168 |
Ejemplares similares
-
Flux Growth, Crystal Structure, and Chemical Bonding
of Yb(2)PdGe(3), an AlB(2) Superstructure
within the Rare-Earth Series
por: Freccero, Riccardo, et al.
Publicado: (2023) -
La(2)Pd(3)Ge(5) and Nd(2)Pd(3)Ge(5) Compounds: Chemical Bonding and
Physical Properties
por: Freccero, Riccardo, et al.
Publicado: (2021) -
Crystal Structure and Magnetism of Noncentrosymmetric
Eu(2)Pd(2)Sn
por: Giovannini, Mauro, et al.
Publicado: (2021) -
Modelling the structural disorder in trigonal-prismatic coordinated transition metal dichalcogenides
por: Ursi, Federica, et al.
Publicado: (2023) -
Formation of trigons in a metal–organic framework: The role of metal–organic polyhedron subunits as meta-atoms
por: Lee, Jiyoung, et al.
Publicado: (2019)