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Bifurcated Halogen Bonding Involving Two Rhodium(I) Centers as an Integrated σ-Hole Acceptor

[Image: see text] The complexes [RhX(COD)](2) (X = Cl, Br; COD = 1,5-cyclooctadiene) form cocrystals with σ-hole iodine donors. X-ray diffraction studies and extensive theoretical considerations indicate that the d(z)(2)-orbitals of two positively charged rhodium(I) centers provide sufficient nucleo...

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Detalles Bibliográficos
Autores principales:	Eliseeva, Anastasiya A., Ivanov, Daniil M., Rozhkov, Anton V., Ananyev, Ivan V., Frontera, Antonio, Kukushkin, Vadim Yu.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8395620/ https://www.ncbi.nlm.nih.gov/pubmed/34467299 http://dx.doi.org/10.1021/jacsau.1c00012

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