Lignin First: Confirming the Role of the Metal Catalyst in Reductive Fractionation

[Image: see text] Rhodium nanoparticles embedded on the interior of hollow porous carbon nanospheres, able to sieve monomers from polymers, were used to confirm the precise role of metal catalysts in the reductive catalytic fractionation of lignin. The study provides clear evidence that the primary...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Lu, van Muyden, Antoine P., Cui, Xinjiang, Fei, Zhaofu, Yan, Ning, Laurenczy, Gabor, Dyson, Paul J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8395662/
https://www.ncbi.nlm.nih.gov/pubmed/34467329
http://dx.doi.org/10.1021/jacsau.1c00018
_version_ 1783744222068736000
author Chen, Lu
van Muyden, Antoine P.
Cui, Xinjiang
Fei, Zhaofu
Yan, Ning
Laurenczy, Gabor
Dyson, Paul J.
author_facet Chen, Lu
van Muyden, Antoine P.
Cui, Xinjiang
Fei, Zhaofu
Yan, Ning
Laurenczy, Gabor
Dyson, Paul J.
author_sort Chen, Lu
collection PubMed
description [Image: see text] Rhodium nanoparticles embedded on the interior of hollow porous carbon nanospheres, able to sieve monomers from polymers, were used to confirm the precise role of metal catalysts in the reductive catalytic fractionation of lignin. The study provides clear evidence that the primary function of the metal catalyst is to hydrogenate monomeric lignin fragments into more stable forms following a solvent-based fractionation and fragmentation of lignin.
format Online
Article
Text
id pubmed-8395662
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-83956622021-08-30 Lignin First: Confirming the Role of the Metal Catalyst in Reductive Fractionation Chen, Lu van Muyden, Antoine P. Cui, Xinjiang Fei, Zhaofu Yan, Ning Laurenczy, Gabor Dyson, Paul J. JACS Au [Image: see text] Rhodium nanoparticles embedded on the interior of hollow porous carbon nanospheres, able to sieve monomers from polymers, were used to confirm the precise role of metal catalysts in the reductive catalytic fractionation of lignin. The study provides clear evidence that the primary function of the metal catalyst is to hydrogenate monomeric lignin fragments into more stable forms following a solvent-based fractionation and fragmentation of lignin. American Chemical Society 2021-04-22 /pmc/articles/PMC8395662/ /pubmed/34467329 http://dx.doi.org/10.1021/jacsau.1c00018 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Chen, Lu
van Muyden, Antoine P.
Cui, Xinjiang
Fei, Zhaofu
Yan, Ning
Laurenczy, Gabor
Dyson, Paul J.
Lignin First: Confirming the Role of the Metal Catalyst in Reductive Fractionation
title Lignin First: Confirming the Role of the Metal Catalyst in Reductive Fractionation
title_full Lignin First: Confirming the Role of the Metal Catalyst in Reductive Fractionation
title_fullStr Lignin First: Confirming the Role of the Metal Catalyst in Reductive Fractionation
title_full_unstemmed Lignin First: Confirming the Role of the Metal Catalyst in Reductive Fractionation
title_short Lignin First: Confirming the Role of the Metal Catalyst in Reductive Fractionation
title_sort lignin first: confirming the role of the metal catalyst in reductive fractionation
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8395662/
https://www.ncbi.nlm.nih.gov/pubmed/34467329
http://dx.doi.org/10.1021/jacsau.1c00018
work_keys_str_mv AT chenlu ligninfirstconfirmingtheroleofthemetalcatalystinreductivefractionation
AT vanmuydenantoinep ligninfirstconfirmingtheroleofthemetalcatalystinreductivefractionation
AT cuixinjiang ligninfirstconfirmingtheroleofthemetalcatalystinreductivefractionation
AT feizhaofu ligninfirstconfirmingtheroleofthemetalcatalystinreductivefractionation
AT yanning ligninfirstconfirmingtheroleofthemetalcatalystinreductivefractionation
AT laurenczygabor ligninfirstconfirmingtheroleofthemetalcatalystinreductivefractionation
AT dysonpaulj ligninfirstconfirmingtheroleofthemetalcatalystinreductivefractionation

Ejemplares similares