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Thin Layer Buckling in Perovskite CsPbBr(3) Nanobelts
[Image: see text] Flexible semiconductor materials, where structural fluctuations and transformation are tolerable and have low impact on electronic properties, focus interest for future applications. Two-dimensional thin layer lead halide perovskites are hailed for their unconventional optoelectron...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8397391/ https://www.ncbi.nlm.nih.gov/pubmed/34181431 http://dx.doi.org/10.1021/acs.nanolett.1c00962 |
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author | Massasa, Emma H. Strassberg, Rotem Vurgaft, Amit Kauffmann, Yaron Cohen, Noy Bekenstein, Yehonadav |
author_facet | Massasa, Emma H. Strassberg, Rotem Vurgaft, Amit Kauffmann, Yaron Cohen, Noy Bekenstein, Yehonadav |
author_sort | Massasa, Emma H. |
collection | PubMed |
description | [Image: see text] Flexible semiconductor materials, where structural fluctuations and transformation are tolerable and have low impact on electronic properties, focus interest for future applications. Two-dimensional thin layer lead halide perovskites are hailed for their unconventional optoelectronic features. We report structural deformations via thin layer buckling in colloidal CsPbBr(3) nanobelts adsorbed on carbon substrates. The microstructure of buckled nanobelts is determined using transmission electron microscopy and atomic force microscopy. We measured significant decrease in emission from the buckled nanobelt using cathodoluminescence, marking the influence of such mechanical deformations on electronic properties. By employing plate buckling theory, we approximate adhesion forces between the buckled nanobelt and the substrate to be F(adhesion) ∼ 0.12 μN, marking a limit to sustain such deformation. This work highlights detrimental effects of mechanical buckling on electronic properties in halide perovskite nanostructures and points toward the capillary action that should be minimized in fabrication of future devices and heterostructures based on nanoperovskites. |
format | Online Article Text |
id | pubmed-8397391 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-83973912021-08-31 Thin Layer Buckling in Perovskite CsPbBr(3) Nanobelts Massasa, Emma H. Strassberg, Rotem Vurgaft, Amit Kauffmann, Yaron Cohen, Noy Bekenstein, Yehonadav Nano Lett [Image: see text] Flexible semiconductor materials, where structural fluctuations and transformation are tolerable and have low impact on electronic properties, focus interest for future applications. Two-dimensional thin layer lead halide perovskites are hailed for their unconventional optoelectronic features. We report structural deformations via thin layer buckling in colloidal CsPbBr(3) nanobelts adsorbed on carbon substrates. The microstructure of buckled nanobelts is determined using transmission electron microscopy and atomic force microscopy. We measured significant decrease in emission from the buckled nanobelt using cathodoluminescence, marking the influence of such mechanical deformations on electronic properties. By employing plate buckling theory, we approximate adhesion forces between the buckled nanobelt and the substrate to be F(adhesion) ∼ 0.12 μN, marking a limit to sustain such deformation. This work highlights detrimental effects of mechanical buckling on electronic properties in halide perovskite nanostructures and points toward the capillary action that should be minimized in fabrication of future devices and heterostructures based on nanoperovskites. American Chemical Society 2021-06-28 2021-07-14 /pmc/articles/PMC8397391/ /pubmed/34181431 http://dx.doi.org/10.1021/acs.nanolett.1c00962 Text en © 2021 American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Massasa, Emma H. Strassberg, Rotem Vurgaft, Amit Kauffmann, Yaron Cohen, Noy Bekenstein, Yehonadav Thin Layer Buckling in Perovskite CsPbBr(3) Nanobelts |
title | Thin Layer Buckling in Perovskite CsPbBr(3) Nanobelts |
title_full | Thin Layer Buckling in Perovskite CsPbBr(3) Nanobelts |
title_fullStr | Thin Layer Buckling in Perovskite CsPbBr(3) Nanobelts |
title_full_unstemmed | Thin Layer Buckling in Perovskite CsPbBr(3) Nanobelts |
title_short | Thin Layer Buckling in Perovskite CsPbBr(3) Nanobelts |
title_sort | thin layer buckling in perovskite cspbbr(3) nanobelts |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8397391/ https://www.ncbi.nlm.nih.gov/pubmed/34181431 http://dx.doi.org/10.1021/acs.nanolett.1c00962 |
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